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Syntheses, characterization, and magnetic properties of two 3D frl topological frameworks constructed from nickel diphosphonates

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Abstract

Two 3D open-framework nickel diphosphonates, [Ni3(H2zdn)2(bpe)2]·4H2O (1) and [Ni3(H2zdn)2(bpy)2]·bpy·4H2O (2) (H5zdn = zoledronic acid, bpe = trans-4,4-vinylenedipyridine, bpy = 4,4′-dipyridyl), have been prepared and structurally characterized. In complex 1, the metal centers are linked by zoledronate ligands to generate a 2D layer, containing 14- and 24-membered rings. These 2D layers are further pillared by the bpe ligands into a 3D network structure with cylindrical channels. Magnetic susceptibility measurements reveal ferrimagnetism at T c = 3.8 and 4.4 K for complexes 1 and 2, respectively.

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Acknowledgments

This project was sponsored by K. C. Wong Magna Fund in Ningbo University and supported by the Scientific Research Fund of Zhejiang Provincial Education Department. The authors thank xi2004 for the refinement of crystal structure data.

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Authors and Affiliations

  1. Crystal Engineering Division, Center of Applied Solid State Chemistry Research, Ningbo University, Ningbo, 315211, People’s Republic of China

    Qing-Jun Niu, Yue-Qing Zheng, Hong-Lin Zhu & Wei Xu

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  1. Qing-Jun Niu
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  2. Yue-Qing Zheng
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  3. Hong-Lin Zhu
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  4. Wei Xu
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Correspondence to Yue-Qing Zheng.

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Niu, QJ., Zheng, YQ., Zhu, HL. et al. Syntheses, characterization, and magnetic properties of two 3D frl topological frameworks constructed from nickel diphosphonates. Transition Met Chem 41, 365–373 (2016). https://doi.org/10.1007/s11243-016-0030-y

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