Skip to main content
SpringerLink
Log in

Pseudohalide anion directed assemblies of two CuII complexes based on 3-(2-pyridyl)-4,5-bis(3-pyridyl)-1,2,4-triazole

  • Published:
Transition Metal Chemistry Aims and scope Submit manuscript

Abstract

Two CuII supramolecular coordination complexes, namely [Cu(L233)(SCN)2] n and [Cu(L233)(N3)2]2 (L233 = 3-(2-pyridyl)-4,5-bis(3-pyridyl)-1,2,4-triazole), have been synthesized by the reactions of L233 with Cu(OAc)2 in the presence of NH4SCN or NaN3. Single-crystal X-ray diffraction analysis reveals that the complex [Cu(L233)(SCN)2] n possesses a 1D zigzag chain, while [Cu(L233)(N3)2]2 shows a binuclear coordination pattern. In both structures, the coordination motifs are further extended to form different supramolecular architectures with the aid of secondary interactions. The structural distinction between these compounds can be ascribed to the directing effect of the ancillary pseudohalide ligands. In addition, the thermal stabilities of both complexes are described and discussed.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Scheme 1
Fig. 2

Similar content being viewed by others

References

  1. Moulton B, Zaworotko MJ (2001) Chem Rev 101:1629

    Article  CAS  Google Scholar 

  2. Evans OR, Lin WB (2002) Acc Chem Res 35:511

    Article  CAS  Google Scholar 

  3. Zhang JP, Huang XC, Chen XM (2009) Chem Soc Rev 38:2385

    Article  CAS  Google Scholar 

  4. Carlucci L, Ciani G, Moret M, Proserpio DM, Rizzato S (2000) Angew Chem Int Ed 39:1506

    Article  CAS  Google Scholar 

  5. Yaghi OM, O’Keeffe M, Ockwig NW, Chae HK, Eddaoudi M, Kim J (2003) Nature 423:705

    Article  CAS  Google Scholar 

  6. Rowsell JLC, Yaghi OM (2005) Angew Chem Int Ed 44:4670

    Article  CAS  Google Scholar 

  7. Sun DF, Ma SQ, Simmons JM, Li JR, Yuan DQ, Zhou HC (2010) Chem Commun 46:1329

    Article  CAS  Google Scholar 

  8. Long LS (2010) CrystEngComm 12:1354

    Article  CAS  Google Scholar 

  9. Li CP, Du M (2011) Chem Commun 47:5958

    Article  CAS  Google Scholar 

  10. Zheng B, Dong H, Bai JF, Li YZ, Li SH, Scheer M (2008) J Am Chem Soc 130:7778

    Article  CAS  Google Scholar 

  11. Pan L, Huang XY, Li J, Wu YG, Zheng NW (2000) Angew Chem Int Ed 39:527

    Article  CAS  Google Scholar 

  12. Tong ML, Chen XM, Batten SR (2003) J Am Chem Soc 125:16170

    Article  CAS  Google Scholar 

  13. Carlucci L, Ciani G, Proserpio DM, Rizzato S (2003) CrystEngComm 5:190

    Article  CAS  Google Scholar 

  14. Du M, Jiang XJ, Zhao XJ (2005) Chem Commun 44:5521

  15. Chen D, Liu YJ, Lin YY, Zhang JP, Chen XM (2011) CrystEngComm 13:3827

    Article  CAS  Google Scholar 

  16. Du M, Jiang XJ, Zhao XJ (2007) Inorg Chem 46:3984

    Article  CAS  Google Scholar 

  17. Khaorapapong N, Pimchan P, Ogawa M (2011) Dalton Trans 40:5964

    Article  CAS  Google Scholar 

  18. Lu WG, Jiang L, Feng XL, Lu TB (2008) Cryst Growth Des 8:986

    Article  CAS  Google Scholar 

  19. Caballero AB, Rodríguez-Diéguez A, Barea E, Quirós M, Salas JM (2010) CrystEngComm 12:3038

    Article  CAS  Google Scholar 

  20. Khan S, Roy S, Bhar K, Ghosh R, Lin CH, Ribas J, Ghosh BK (2013) Inorg Chim Acta 398:40

    Article  CAS  Google Scholar 

  21. Biswas S, Diaz C, Ghosh A (2013) Polyhedron 51:96

    Article  CAS  Google Scholar 

  22. Klingele MH, Brooker S (2004) Eur J Org Chem 2004:3422

  23. Spek AL (2003) PLATON: a multipurpose crystallographic tool. Untrecht University, Netherlands

    Google Scholar 

  24. Sheldrick GM (1996) SADABS: siemens area detector absorption corrected software. University of Göttingen, Germany

    Google Scholar 

  25. Bruker AXS (1998) SAINT software reference manual. Madison, WI

  26. Sheldrick GM (1997) SHELXS-97: program for the solution of crystal structures. University of Göttingen, Germany

    Google Scholar 

  27. Sheldrick GM (1997) SHELXL-97: program for the refinement of crystal structures. University of Göttingen, Germany

    Google Scholar 

  28. Addison AW, Rao TN, Reedijk J, Van Rijn J, Verschoor GC (1984) J Chem Soc Dalton Trans 1349

Download references

Acknowledgments

This work was financially supported by the National Natural Science Foundation of China (No. 21101116) and Innovation Foundation of Tianjin Normal University (No. 52XC1402).

Author information

Authors and Affiliations

  1. College of Chemistry, Tianjin Key Laboratory of Structure and Performance for Functional Molecules, MOE Key Laboratory of Inorganic–Organic Hybrid Functional Material Chemistry, Tianjin Normal University, Tianjin, 300387, People’s Republic of China

    Bo-Lan Liu, Na Wu, Cheng-Peng Li & Jing Chen

Authors
  1. Bo-Lan Liu
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Na Wu
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Cheng-Peng Li
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Jing Chen
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Jing Chen.

Electronic supplementary material

Below is the link to the electronic supplementary material.

Supplementary material 1 (DOC 3529 kb)

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Liu, BL., Wu, N., Li, CP. et al. Pseudohalide anion directed assemblies of two CuII complexes based on 3-(2-pyridyl)-4,5-bis(3-pyridyl)-1,2,4-triazole. Transition Met Chem 40, 341–345 (2015). https://doi.org/10.1007/s11243-015-9922-5

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11243-015-9922-5

Keywords

Search

Navigation