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Synthesis, crystal structures and magnetic properties of three complexes containing bis(maleonitriledithiolate) copper(II) anion and meta-substituted benzyl isoquinolinium cations

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Abstract

Three complexes, [3RBzIQl]2[Cu(mnt)2] (mnt2− = maleonitriledithiolate; [3RBzIQl]+ = 1-(3′-R-benzyl)isoquinolinium, R = Cl (1), I (2) or NO2 (3)), have been prepared and characterized by spectroscopic and physicochemical methods as well as by X-ray crystallography. The [Cu(mnt)2]2− anions formed a 1D chain in complex 1, a dimer in 2 and a sheet structure in 3 through C···N and/or N···N interactions. The neighboring dimers of the cations arranged in a boat-type pattern stack into columns through weak π···π, Cl···π or O···π, C–H···π interactions. The anions and cations stack together into a columnar structure with a ···A–CC–A–CC–A··· sequence. The magnetic susceptibilities measured in the temperature range 2.0–300 K reveal that complex 1 undergoes a change from weak ferromagnetic to antiferromagnetic exchange around 132 K, while 2 shows antiferromagnetic behavior and 3 shows a weak ferromagnetic interaction when the temperature is lowered.

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Acknowledgments

This research was supported by the Science and Technology Project (No. 2014A010105037) from Guangdong Science and Technology Department and the university students’ innovative training project (No. 201410564195) from Education Department of Guangdong Province.

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Authors and Affiliations

  1. College of Materials and Energy, Institute of Biomaterial, South China Agricultural University, Guangzhou, 510642, People’s Republic of China

    Zheng Zhang, Wan-Er He, Xuan Liao, Xiao-Min Chen, Xue-Ni Lin, Zi-Mei Yao, Chun-Lin Ni, Jia-Rong Zhou, Le-Min Yang & Yao-Mou Zhang

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  1. Zheng Zhang
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  2. Wan-Er He
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  3. Xuan Liao
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Correspondence to Chun-Lin Ni or Yao-Mou Zhang.

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Zhang, Z., He, WE., Liao, X. et al. Synthesis, crystal structures and magnetic properties of three complexes containing bis(maleonitriledithiolate) copper(II) anion and meta-substituted benzyl isoquinolinium cations. Transition Met Chem 41, 249–259 (2016). https://doi.org/10.1007/s11243-015-0016-1

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  • DOI: https://doi.org/10.1007/s11243-015-0016-1

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