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Nickel(II) and manganese(II) metal–organic networks driven by 2,2′-bipyridine-5,5′-dicarboxylate blocks: synthesis, structural features, and magnetic properties

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Abstract

Two compounds, namely a 2D coordination polymer {[Ni(µ 3-bpdc)(H2O)]·H2O} n (1) and a 3D metal–organic framework (MOF) [Mn(µ 4-bpdc)(phen)] n (2), were generated by a hydrothermal self-assembly from the corresponding metal(II) chlorides, 2,2′-bipyridine-5,5′-dicarboxylic acid (H2bpdc) as a main building block, and an optional ancillary 1,10-phenanthroline (phen) ligand. The obtained products were characterized by IR spectroscopy, elemental, thermogravimetric, powder and single-crystal X-ray diffraction analyses. Compound 1 possesses a 2D double-layered network with the plane SP KIa topology defined by the point symbol of (82.10), which is further extended into a 3D supramolecular architecture via hydrogen bonds. MOF 2 features a 3D net with the pts topology and point symbol of (42.84). The magnetic properties for both compounds were also investigated, indicating antiferromagnetic interactions between the adjacent metal ions.

Graphical Abstract

Two 2D and 3D metal–organic networks driven by a multifunctional building block were self-assembled and fully characterized; their structural, topological, and magnetic features were investigated.

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Acknowledgments

This work was supported by Guangdong Province Higher Vocational Colleges & Schools Pearl River Scholar Funded Scheme (2015), Science and Technology Planning Project of Guangzhou (Project No. 201510010170), Science and Technology Planning Project of Guangdong Province (Project No. 2012A020603023), and the Natural Science Foundation of Guangdong Industry Technical College (Project No. KJ201301). AMK acknowledges the FCT (PTDC/QUI–QUI/121526/2010).

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Authors and Affiliations

  1. Guangdong Vocational School of Polytechnic, Guangzhou, 510500, People’s Republic of China

    Guo-Ming Zhang

  2. Department of Environmental Engineering, Guangdong Industry Technical College, Guangzhou, 510300, People’s Republic of China

    Yu Li

  3. School of Pharmacy and College of Traditional Chinese Medicine, Guangdong Pharmaceutical University, Guangzhou, 510006, People’s Republic of China

    Xun-Zhong Zou & Jing-An Zhang

  4. Key Laboratory of Nonferrous Metal Chemistry and Resources Utilization of Gansu Province, College of Chemistry and Chemical Engineering Lanzhou University, Lanzhou, 730000, People’s Republic of China

    Jin-Zhong Gu

  5. Centro de Química Estrutural, Complexo I, Instituto Superior Técnico, Universidade de Lisboa, Av. Rovisco Pais, 1049-001, Lisbon, Portugal

    Alexander M. Kirillov

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  1. Guo-Ming Zhang
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  2. Yu Li
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  3. Xun-Zhong Zou
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  4. Jing-An Zhang
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  5. Jin-Zhong Gu
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  6. Alexander M. Kirillov
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Corresponding authors

Correspondence to Yu Li or Jin-Zhong Gu.

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Zhang, GM., Li, Y., Zou, XZ. et al. Nickel(II) and manganese(II) metal–organic networks driven by 2,2′-bipyridine-5,5′-dicarboxylate blocks: synthesis, structural features, and magnetic properties. Transition Met Chem 41, 153–160 (2016). https://doi.org/10.1007/s11243-015-0007-2

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  • DOI: https://doi.org/10.1007/s11243-015-0007-2

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