Skip to main content
SpringerLink
Log in

Zinc(II), nickel(II) and cadmium(II) coordination polymers based on the ligand oxamide N,N-bis(4-phthalic acid): synthesis, structural characterization and magnetic properties

  • Published:
Transition Metal Chemistry Aims and scope Submit manuscript

Abstract

Three coordination polymers based on the new ligand oxamide N,N-bis(4-phthalic acid), namely [Zn(L)0.5-(2,2′-bpy)] n (1), [Ni2(2,2′-bpy)4(µ 2-Ox)]L·3H2O (2) and [Cd(L)(1,10-phen)] (3) [L = oxamide N,N-bis(4-phthalic acid)], (2,2′-bpy = 2,2′-bipyridine), (1,10-phen = 1,10-phenanthroline), have been solvothermally synthesized and structurally characterized by single-crystal X-ray diffraction: compound 1 is one-dimensional ladder-like coordination polymer, compound 2 exhibits a three-dimensional structure resulting in extensive hydrogen bonds built with the help of lattice water molecules, compound 3 also exhibits a three-dimensional supramolecular structure. All compounds were also characterized by elemental analysis, IR spectra and thermogravimetric analysis; furthermore, the magnetic measurements for 2 reveal antiferromagnetic coupling between the nickel(II) ions.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Scheme 1
Scheme 2
Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6

Similar content being viewed by others

References

  1. Shin JW, Bae JM, Kim C, Min KS (2013) Inorg Chem 52:2265

    Article  CAS  Google Scholar 

  2. Coronado E, Galan-Mascaros JR, Gomez-Garcia CJ, Laukhin V (2000) Nature 408:447

    Article  CAS  Google Scholar 

  3. Li S-L, Lan Y-Q, Ma J-F, Yang J, Wei G-H, Zhang L-P, Su Z-M (2008) Cryst Growth Des 8:675

    Article  CAS  Google Scholar 

  4. Beitone L, Huguenard C, Gansmuller A, Henry M, Taulelle F, Loiseau T, Férey G (2003) J Am Chem Soc 125:9102

    Article  CAS  Google Scholar 

  5. Zhang Z-H, Okamura T-A, Hasegawa Y, Kawaguchi H, Kong L-Y, Sun W-Y, Ueyama N (2005) Inorg Chem 44:6219

    Article  CAS  Google Scholar 

  6. Ockwig NW, Delgado-Friedrichs O, O’Keeffe M, Yaghi OM (2005) Acc Chem Res 38:176

    Article  CAS  Google Scholar 

  7. Moulton B, Zaworotko M (2001) Chem Rev 101:1629

    Article  CAS  Google Scholar 

  8. Wang R, Hong M, Luo J, Cao R, Shi Q, Weng J (2002) Eur J Inorg Chem 2002:2904

    Article  Google Scholar 

  9. Ruiz R, Faus J, Lloret F, Julve M, Journaux Y (1999) Coord Chem Rev 193–195:1069–1117

    Article  Google Scholar 

  10. Escuer A, Vicente R, Ribas J, Costa R, Solanslb X (1992) Inorg Chem 31:2627

    Article  CAS  Google Scholar 

  11. Journaux Y, Sletten J, Kahn O (1985) Inorg Chem 24:4063

    Article  CAS  Google Scholar 

  12. Nakatani K et al (1989) J Am Chem Soc 111:5739

    Article  CAS  Google Scholar 

  13. Dul M-C et al (2009) J Am Chem Soc 131:14614

    Article  CAS  Google Scholar 

  14. Hulvey Z, Ayala E, Furman JD, Forster PM, Cheetham AK (2009) Cryst Growth Des 9:11

    Article  Google Scholar 

  15. Schilt R (1969) Analytical applications of 1,10-phenanthroline and related compounds. Pergamon, London

    Google Scholar 

  16. Wang L, You W, Huang W, Wang C, You X-Z (2009) Inorg Chem 48:10

    Article  Google Scholar 

  17. Wang X-L, Chen Y-Q, Gao Q, Lin H-Y, Liu G-C, Zhang J-X, Tian A-X (2010) Cryst Growth Des 10:5

    CAS  Google Scholar 

  18. Pallemberg AJ, Marschner TM, Barnhart DM (1997) Polyhedron 16:2711

    Article  Google Scholar 

  19. Slough GA, Krchnák V, Helquist P, Canham SM (2004) Org Lett 6:17

    Article  Google Scholar 

  20. Chen W, Yuan H-M, Wang J-Y, Liu Z-Y, Xu J-J, Yang M, Chen J-S (2003) J Am Chem Soc 125:9266

    Article  CAS  Google Scholar 

  21. Ganesan SV, Natarajan S (2004) Inorg Chem 43:198

    Article  CAS  Google Scholar 

  22. Kahn O (1985) Angew Chem Int Ed Engl 24:834

    Article  Google Scholar 

  23. Battaglia LP, Bianchi A, Bonamartini Corradi A, Garcia-Espafia E, Micheloni M, Julve M (1988) Inorg Chem 27:4174

    Article  CAS  Google Scholar 

  24. Girerd JJ, Kahn O, Verdaguer M (1980) Inorg Chem 19:274

    Article  CAS  Google Scholar 

  25. Julve M, Verdaguer M, Gleizes A, Philoche-Levisalles M, Kahn A, Philoche-Levisalles M, Kahn O (1984) Inorg Chem 23:3808

    Article  CAS  Google Scholar 

  26. Alcock NW, Moore P, Omar HAA (1987) Acta Crystallogr Sect C Cryst Struct Commun C43(11):2074

    Article  CAS  Google Scholar 

  27. Huang Y-G et al (2007) J Mol Struct 830:85

    Article  CAS  Google Scholar 

  28. Lan A, Chen L, Yuan D, Huang Y, Hong M, Wang X (2011) Polyhedron 30:47

    Article  CAS  Google Scholar 

  29. Romań P, Guzmań-Miralles C, Luque A, Beitia JI, Cano J, Lloret F, Julve M, Alvarez S (1996) Inorg Chem 35:3741

    Article  Google Scholar 

Download references

Acknowledgments

We are very grateful for the support of this study by the National Natural Science Foundation of China (Nos. 21461023 and 21361023), Fundamental Research Funds for the Gansu Universities.

Author information

Authors and Affiliations

  1. College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou, 730070, People’s Republic of China

    Ibrahim Omar Osman, Yan Fan, Chen Hou, Chang-Dai Si, Dong-Chen Hu, Ya-Jun Wu & Jia-Cheng Liu

  2. State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing, 210093, People’s Republic of China

    Jia-Cheng Liu

  3. Faculty of Education, Zalingei University, Zalingei, Sudan

    Ibrahim Omar Osman

  4. College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, 361005, People’s Republic of China

    Wen-Ting Deng

Authors
  1. Ibrahim Omar Osman
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Wen-Ting Deng
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Yan Fan
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Chen Hou
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Chang-Dai Si
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. Dong-Chen Hu
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. Ya-Jun Wu
    View author publications

    You can also search for this author in PubMed Google Scholar

  8. Jia-Cheng Liu
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Jia-Cheng Liu.

Electronic supplementary material

Below is the link to the electronic supplementary material.

Supplementary material 1 (DOCX 215 kb)

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Osman, I.O., Deng, WT., Fan, Y. et al. Zinc(II), nickel(II) and cadmium(II) coordination polymers based on the ligand oxamide N,N-bis(4-phthalic acid): synthesis, structural characterization and magnetic properties. Transition Met Chem 41, 133–141 (2016). https://doi.org/10.1007/s11243-015-0005-4

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11243-015-0005-4

Keywords

Search

Navigation