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Cobalt(II) complexes of a new imidazolium-tagged thiadiazole ligand with bis(trifluormethylsulfonyl)imide or tetraisothiocyanato cobaltate as counterion

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Abstract

The ligand pentanoic acid [5-(2-pyridyl)-1,3,4-thiadiazol-2-yl]-amide-5-(3-ethyl)-3H-1-imidazolium bis(trifluormethylsulfonyl)imide (LNTf2) has been prepared and used for the complexation with “Co(NCS)2”. Compounds [CoII(L)2(NCS)2][Co(NCS)4] and [CoII(L)2(NCS)2](NTf2)2 of L + have been structurally characterised by single-crystal X-ray diffraction analyses and are rare examples of Werner-type 3d transition metal complexes with chromophores of neutral charge but cationic coordination entities, due to imidazolium tags.

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References

  1. Klingele MH, Brooker S (2003) Coord Chem Rev 241:119

    Article  CAS  Google Scholar 

  2. Kitchen JA, Brooker S (2008) Coord Chem Rev 252:2072

    Article  CAS  Google Scholar 

  3. Aromí G, Barrios LA, Roubeau O, Gamez P (2011) Coord Chem Rev 255:485

    Article  Google Scholar 

  4. Klingele J, Kaase D, Hilgert J, Steinfeld G, Klingele MH, Lach J (2010) Dalton Trans 39:4495

    Article  CAS  Google Scholar 

  5. Kaase D, Gotzmann C, Rein S, Lan Y, Kacprzak S, Klingele J (2014) Inorg Chem 53:5546

    Article  CAS  Google Scholar 

  6. Klingele J, Kaase D, Huxel T, Gotzmann C, Lan Y (2013) Polyhedron 52:500

    Article  CAS  Google Scholar 

  7. Klingele J, Kaase D, Klingele MH, Lach J, Demeshko S (2010) Dalton Trans 39:1689

    Article  CAS  Google Scholar 

  8. Klingele J, Kaase D, Klingele MH, Lach J (2012) Dalton Trans 41:1397

    Article  CAS  Google Scholar 

  9. Klingele J, Kaase D, Schmucker M, Chastanet G, Létard J-F (2013) Inorg Chem 52:6000

    Article  CAS  Google Scholar 

  10. Klingele J, Kaase D, Schmucker M, Meier L (2013) Eur J Inorg Chem 28:4931

    Google Scholar 

  11. Bentiss F, Lagrenée M, Wignacourt JP, Holt EM (2002) Polyhedron 21:403

    Article  CAS  Google Scholar 

  12. Bentiss F, Lagrenée M, Mentré O, Conflant P, Vezin H, Wignacourt JP, Holt EM (2004) Inorg Chem 43:1865

    Article  CAS  Google Scholar 

  13. Huxel T, Leone S, Lan Y, Demeshko S, Klingele J (2014) Eur J Inorg Chem 2014:3114

  14. Klingele J, Dechert S, Meyer F (2009) Coord Chem Rev 253:2698

    Article  CAS  Google Scholar 

  15. Klingele J, Steinfeld G, Klingele MH (2010) Trans Met Chem 35:65

    Article  CAS  Google Scholar 

  16. Kitchen JA, White NG, Boyd M, Moubaraki B, Murray KS, Boyd PDW, Brooker S (2009) Inorg Chem 48:6670

    Article  CAS  Google Scholar 

  17. Klingele J, Scherer H, Klingele MH (2009) Z Anorg Allg Chem 635:2279

    Article  CAS  Google Scholar 

  18. Zhu D, Xu Y, Yu Z, Guo Z, Sang H, Liu T, You X (2002) Chem Mater 14:838

    Article  CAS  Google Scholar 

  19. Juríćek M, Kouwer PHJ, Rowan AE (2011) Chem Commun 47:8740

    Article  Google Scholar 

  20. Xu Z, Meng W, Li H, Hou H, Fan Y (2014) Inorg Chem 53:3260

    Article  CAS  Google Scholar 

  21. Zhang X, Xing N, Bai F, Wan L, Shan H, Hou Y, Xing Y, Shi Z (2013) CrystEngComm 15:9135

    Article  CAS  Google Scholar 

  22. Neudeck S, Maji S, Lopez I, Meyer S, Meyer F, Llobet A (2014) J Am Chem Soc 136:24

    Article  CAS  Google Scholar 

  23. Poater A (2014) Catal Commun 44:2

    Article  CAS  Google Scholar 

  24. Dondoni A (2010) Org Biomol Chem 8:3366

    Article  CAS  Google Scholar 

  25. Terenzi A, Barone G, Piccionello AP, Giorgi G, Guarcello A, Portanova P, Calvaruso G, Buscemi S, Vivona N, Pace A (2010) Dalton Trans 39:9140

    Article  CAS  Google Scholar 

  26. Pace A, Pierro P (2009) Org Biomol Chem 7:4337

    Article  CAS  Google Scholar 

  27. Sato H, Miya L, Mitsumoto K, Matsumoto T, Shiga T, Newton GN, Oshio H (2013) Inorg Chem 52:9714

    Article  CAS  Google Scholar 

  28. Schneider B, Demeshko S, Neudeck S, Dechert S, Meyer F (2013) Inorg Chem 52:13230

    Article  CAS  Google Scholar 

  29. van Koningsbruggen PJ (2004) Top Curr Chem 233:123

    Article  Google Scholar 

  30. Hogue RW, Miller RG, White NG, Feltham HLC, Jameson GNL, Brooker S (2014) Chem Commun 50:435

    Article  Google Scholar 

  31. Bentiss F, Lagrenée M, Vezin H, Wignacourt J-P, Holt EM (2004) Polyhedron 23:1903

    Article  CAS  Google Scholar 

  32. Zheng X-F, Wan X-S, Liu W, Niu C-Y, Kou C-H (2006) Z Kristallogr New Cryst Struct 221:543

    CAS  Google Scholar 

  33. Wan X-S, Ning A-M, Hou S-C, Niu C-Y, Kou C-H, Dang Y-L (2007) Z Kristallogr New Cryst Struct 222:153

    CAS  Google Scholar 

  34. Renaud E, Russell RB, Fortier S, Brown SJ, Baird MC (1991) J Organomet Chem 419:403

    Article  CAS  Google Scholar 

  35. Kalck P, Monteil F (1992) Adv Organomet Chem 34:219

    CAS  Google Scholar 

  36. Joó F (2002) Aqueous organometallic catalysis. Kluwer Academic Publishers, Dordrecht

    Google Scholar 

  37. Cadierno V, Francos J, Gimeno J (2008) Chem Eur J 14:6601

    Article  CAS  Google Scholar 

  38. Šebesta R, Kmentová I, Toma Š (2008) Green Chem 10:484

    Article  Google Scholar 

  39. Dyson PJ, Geldbach TJ (2005) Catalysis by metal complexes. Springer, Dordrecht

    Google Scholar 

  40. Oliveri IP, Failla S, Malandrino G, Di Bella S (2011) New J Chem 35:2826

    Article  CAS  Google Scholar 

  41. Sato K, Sadamitsu Y, Arai S, Yamagishi T (2007) Tetrahedron Lett 48:1493

    Article  CAS  Google Scholar 

  42. Moret M-E, Chaplin AB, Lawrence AK, Scopelliti R, Dyson PJ (2005) Organometallics 24:4039

    Article  CAS  Google Scholar 

  43. Barthes C, Lepetit C, Canac Y, Duhayon C, Zargarian D, Chauvin R (2013) Inorg Chem 52:48

    Article  CAS  Google Scholar 

  44. Bravo MJ, Favier I, Saffon N, Ceder RM, Muller G, Gómez M, Rocamora M (2014) Organometallics 33:771

    Article  CAS  Google Scholar 

  45. Schottenberger H, Wurst K, Horvath UEI, Cronje S, Lukasser J, Polin J, McKenzie JM, Raubenheimer HG (2003) Dalton Trans 22:4275

    Article  Google Scholar 

  46. Nyamori VO, Gumede M, Bala MD (2010) J Organomet Chem 695:1126

    Article  CAS  Google Scholar 

  47. Yoshida Y, Saito G (2011) In: Kokorin A (ed) Ionic liquids: theory, properties, new approaches. InTech, Rijeka

    Google Scholar 

  48. Tan R, Yin D, Yu N, Jin Y, Zhao H, Yin D (2008) J Catal 255:287

    Article  CAS  Google Scholar 

  49. dos Santos MR, Gomes AF, Gozzo FC, Suarez PAZ, Neto BAD (2012) ChemSusChem 5:2383

    Article  Google Scholar 

  50. Prodius D, Macaev F, Stingaci E, Pogrebnoi V, Mereacre V, Novitchi G, Kostakis GE, Anson CE, Powell AK (2013) Chem Commun 49:1915

    Article  CAS  Google Scholar 

  51. Ambrose K, Hurisso BB, Singer R (2013) Can J Chem 91:1258

    Article  CAS  Google Scholar 

  52. Song K-M, Gao H-Y, Liu F-S, Pan J, Guo L-H, Za S-B, Wu Q (2009) Catal Lett 131:566

    Article  CAS  Google Scholar 

  53. Naik PU, McManus GJ, Zaworotko MJ, Singer RD (2008) Dalton Trans 36:4834

    Article  Google Scholar 

  54. Crees RS, Cole ML, Hanton LR, Sumby CJ (2010) Inorg Chem 49:1712

    Article  CAS  Google Scholar 

  55. Sheldrick GM (2008) Acta Crystallogr Sect A 64:112

    Article  CAS  Google Scholar 

  56. Schaefer FC, Peters GA (1961) J Org Chem 26:412

    Article  CAS  Google Scholar 

  57. Hegar G (1969) DE1925654, Bundesrepublik Deutschland

  58. Drew MGB, Harding CJ, McKee V, Morgan GG, Nelson J (1995) J Chem Soc Chem Commun 10:1035

    Article  Google Scholar 

  59. Goodwin HA (2004) Top Curr Chem 234:23

    Article  CAS  Google Scholar 

  60. Sonar S, Ambrose K, Hendsbee AD, Masuda JD, Singer RD (2012) Can J Chem 90:60

    Article  CAS  Google Scholar 

  61. dos Santos MR, Diniz JR, Arouca AM, Gomes AF, Gozzo FC, Tamborim SM, Parize AL, Suarez PAZ, Neto BAD (2012) ChemSusChem 5:716

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Acknowledgments

This work was supported by the European Social Fund and the Ministry of Science, Research and the Arts Baden–Württemberg within the Margarete-von-Wrangell-Program, by the Deutsche Forschungsgemeinschaft (DFG) and by the University of Freiburg. The authors are indebted to Dominic Kaase and Dr. Harald Scherer for support on X-ray crystallography and NMR spectroscopy, respectively. J. K. thanks Prof. Ingo Krossing and Prof. Harald Hillebrecht for their generous and continuous support.

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  1. Institut für Anorganische und Analytische Chemie, Albert-Ludwigs-Universität Freiburg, Albertstr. 21, 79104, Freiburg, Germany

    Timo Huxel & Julia Klingele

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  1. Timo Huxel
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  2. Julia Klingele
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Correspondence to Julia Klingele.

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Huxel, T., Klingele, J. Cobalt(II) complexes of a new imidazolium-tagged thiadiazole ligand with bis(trifluormethylsulfonyl)imide or tetraisothiocyanato cobaltate as counterion. Transition Met Chem 40, 61–68 (2015). https://doi.org/10.1007/s11243-014-9890-1

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