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Hydrothermal syntheses, crystal structures and properties of two cobalt(II) complexes constructed from 5-(isonicotinamido)isophthalic acid

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Abstract

Two Co(II) complexes, [Co(INAIP)(dib)]·4H2O and [Co(INAIP)(phen)(H2O)]·H2O have been synthesized by the reaction of 5-(isonicotinamido)isophthalic acid (H2INAIP) and CoSO4·7H2O, as well as N-donor ligands, namely 1,4-di(1-imidazolyl)benzene (dib) and 1,10-phenanthroline (phen) under hydrothermal conditions. Single-crystal X-ray diffraction analysis indicates that [Co(INAIP)(dib)]·4H2O has a two-dimensional (2D) double-layer network structure with a (4, 4) topology, while [Co(INAIP)(phen)(H2O)]·H2O displays a one-dimensional chain structure, extending to a 2D net through the π–π interactions. In addition, the photoluminescence and degradation of methyl orange in a Fenton-like process using the complexes as catalysts were investigated.

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References

  1. Mrozinski J (2005) Coord Chem Rev 249:2534–2548

    Article  CAS  Google Scholar 

  2. Banerjee R, Phan A, Wang B, Knobler C, Furukawa H, O’Keeffe M, Yaghi OM (2008) Science 319:939–943

    Article  CAS  Google Scholar 

  3. Gade LH (2002) Acc Chem Res 35:575–582

    Article  CAS  Google Scholar 

  4. Xiong K, Jiang F, Yang M, Wu M, Feng R, Xu W, Hong M (2012) Dalton Trans 41:540–545

    Article  CAS  Google Scholar 

  5. Benmansour S, Setifi F, Triki S, Gomez-Garcia CJ (2012) Inorg Chem 51:2359–2365

    Article  CAS  Google Scholar 

  6. Li CP, Du M (2011) Chem Commun 47:5958–5972

    Article  CAS  Google Scholar 

  7. Timothy RC, Zheng YR, Peter JS (2013) Chem Rev 113:734–777

    Article  Google Scholar 

  8. Furukawa H, Kim J, Ockwig NW, O’Keeffe M, Yaghi OM (2008) J Am Chem Soc 130:11650–11661

    Article  CAS  Google Scholar 

  9. Zheng B, Dong H, Bai JF, Li YZ, Li SH, Scheer MJ (2008) J Am Chem Soc 130:7778–7779

    Article  CAS  Google Scholar 

  10. Hao JM, Li YH, Li HH, Cui GH (2014) Transition Met Chem 39:1–8

    Article  CAS  Google Scholar 

  11. Sun DF, Ke YX, Mattox TM, Ooro BA, Zhou HC (2005) Chem Commun 43:5447–5449

    Article  Google Scholar 

  12. Chen MS, Chen M, Takamizawa S, Okamurm T-A, Fan J, Sun WY (2011) Chem Commun 47:3787–3789

    Article  CAS  Google Scholar 

  13. Chen MS, Bai ZS, Okamurm T-A, Su Z, Chen SS, Sun WY, Ueyama N (2010) CrystEngComm 12:1935–1944

    Article  CAS  Google Scholar 

  14. Chen MS, Chen M, Okamurm T-A, Sun WY, Ueyama N (2011) Micropor Mesopor Mat 139:25–30

    Article  CAS  Google Scholar 

  15. Chen MS, Luo L, Chen SS, Su Z, Sun WY (2010) Chin J Inorg Chem 26:2227–2232

    CAS  Google Scholar 

  16. Chen MS, Tan XW, Zhang CH, Kuang DZ (2011) Z Anorg Allg Chem 637:1220–1223

    Article  CAS  Google Scholar 

  17. Qin L, Liu LW, Du X, Cui GH (2013) Transit Met Chem 38:85–91

    Article  CAS  Google Scholar 

  18. Sheldrick GM (2003) SADABS, program for empirical absorption correction of area detector data. University of Göttingen, Göttingen (Germany)

    Google Scholar 

  19. Sheldrick GM (2008) Acta Crystallogr A64:112–122

    Article  Google Scholar 

  20. Blatov VA Multipurpose crystallochemical analysis with the program package TOPOS. See also: Blatov VA (2006) IUCr CompComm Newsletter 7:4–38

Download references

Acknowledgments

This work was supported by the National Natural Science Foundation of China (No. 21461004), the Key Project of Science and Technology Plan of Hunan Province (No. 2012FJ2002), the China Postdoctoral Science Foundation (No. 2014M552534XB), the Scientific Research Fund of Hunan Provincial Education Department (14A021), the Foundation of Key Laboratory of Functional Organometallic Materials, University of Hunan Province (No. 13K06), Science and Technology Innovative Research Team in Higher Educational Institutions of Hunan Province and the Hunan Provincial Key Discipline Construction.

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Authors and Affiliations

  1. Key Laboratory of Functional Organometallic Materials, Department of Chemistry and Materials Science, Hengyang Normal University, Hengyang, 421008, Hunan, People’s Republic of China

    Man-Sheng Chen, Yi-Fang Deng, Chun-Hua Zhang, Jin-Sheng Xu & Zheng-Ji Yi

  2. Key Laboratory for the Chemistry and Molecular Engineering of Medicinal Resources (Ministry of Education of China), School of Chemistry and Pharmaceutical Sciences, Guangxi Normal University, Guilin, 541004, People’s Republic of China

    Man-Sheng Chen & Fu-Pei Liang

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  1. Man-Sheng Chen
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  2. Yi-Fang Deng
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  3. Chun-Hua Zhang
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Correspondence to Jin-Sheng Xu or Fu-Pei Liang.

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Chen, MS., Deng, YF., Zhang, CH. et al. Hydrothermal syntheses, crystal structures and properties of two cobalt(II) complexes constructed from 5-(isonicotinamido)isophthalic acid. Transition Met Chem 39, 901–907 (2014). https://doi.org/10.1007/s11243-014-9874-1

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  • DOI: https://doi.org/10.1007/s11243-014-9874-1

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