Skip to main content
SpringerLink
Log in

Pseudo-capsular behaviour of two trans-coordinated calixarenyl phosphines

  • Published:
Transition Metal Chemistry Aims and scope Submit manuscript

Abstract

The square-planar complex trans-[PtCl2L2] (L = 5-diphenylphosphinyl-25,26,27,28-tetrabenzyloxy-calix[4]arene) was prepared in two steps from [PtCl2(cod)] (cod = 1,5-cyclooctadiene) and the corresponding phosphine. In the solid state, the calixarene moieties adopt a typical pinched cone conformation; they are both turned towards the Cl–Pt–Cl rod, thereby forming a capsule that hosts the platinum centre.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Scheme 1
Fig. 1
Fig. 2

Similar content being viewed by others

References

  1. Lejeune M, Jeunesse C, Matt D, Kyritsakas N, Welter R, Kintzinger J-P (2002) J Chem Soc Dalton Trans 1642–1650

  2. Sameni S, Lejeune M, Jeunesse C, Matt D, Welter R (2009) Dalton Trans 7912–7923

  3. Monnereau L, Sémeril D, Matt D, Toupet L (2010) Chem Eur J 16:9237–9247

    Article  CAS  Google Scholar 

  4. Monnereau L, Sémeril D, Matt D (2011) Chem Commun 47:6626–6628

    Article  CAS  Google Scholar 

  5. Gerasko OA, Sokolov MN (2004) Fedin VP 76:1633–1646

    CAS  Google Scholar 

  6. Altomare A, Burla MC, Camalli M, Cascarano G, Giacovazzo C, Guagliardi A, Moliterni AGG, Polidori G, Spagna R (1998) J Appl Crystallogr 31:74–77

    Article  CAS  Google Scholar 

  7. Sheldrick GM (2008) Acta Cryst A64:112–122

    Google Scholar 

  8. Gutsche CD (1989) Calixarenes, in monographs in supramolecular chemistry, In: Stoddart JF (ed), RSC, Cambridge

  9. SPARTAN Version 1.1.8, Wawefunction, Irvine (USA) 1997

  10. Jircitano AJ, Mertes KB (1985) Inorg Chim Acta 103:L11–L13

    Article  CAS  Google Scholar 

  11. Corcoran C, Fawcett J, Friedrichs S, Holloway JH, Hope EG, Russell DR, Saunders GC, Stuart AM (2000) J Chem Soc Dalton Trans 161–172

  12. Johansson MH, Otto S (2000) Acta Cryst C56:e12–e15

    CAS  Google Scholar 

Download references

Acknowledgments

The University of Strasbourg is gratefully acknowledged for a grant to L.M.

Author information

Authors and Affiliations

  1. Laboratoire de Chimie Inorganique Moléculaire et Catalyse, UMR 7177 CNRS, Université de Strasbourg, 1 Rue Blaise Pascal, 67008, Strasbourg Cedex, France

    Laure Monnereau, David Sémeril & Dominique Matt

  2. Institut de Physique, UMR 6251 CNRS, Université de Rennes 1, Campus de Beaulieu, 35042, Rennes Cedex, France

    Loïc Toupet

Authors
  1. Laure Monnereau
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. David Sémeril
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Dominique Matt
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Loïc Toupet
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding authors

Correspondence to David Sémeril or Dominique Matt.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Monnereau, L., Sémeril, D., Matt, D. et al. Pseudo-capsular behaviour of two trans-coordinated calixarenyl phosphines. Transition Met Chem 38, 821–825 (2013). https://doi.org/10.1007/s11243-013-9754-0

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11243-013-9754-0

Keywords

Search

Navigation