Skip to main content
SpringerLink
Log in

Syntheses, crystal structures and properties of two nickel(II) coordination polymers constructed from 5-(isonicotinamido)isophthalic acid

  • Published:
Transition Metal Chemistry Aims and scope Submit manuscript

Abstract

Two Ni(II) metal–organic frameworks, [Ni(INAIP)(DMF)]·0.5DMF and [Ni(INAIP)(H2O)]·2H2O, have been synthesized by the reaction of 5-(isonicotinamido)isophthalic acid (H2INAIP) with NiSO4·6H2O using different reaction solvents. Single-crystal X-ray diffraction analysis indicates that [Ni(INAIP)(DMF)]·0.5DMF has a twofold interpenetrated three-dimensional (3D) framework with sra topology, while [Ni(INAIP)(H2O)]·2H2O has a two-dimensional (2D) network structure with a 4-connected (43·63) topology. In addition, the magnetic and adsorption properties of the complexes were explored.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4

Similar content being viewed by others

References

  1. Paz FAA, Klinowski J, Vilela SMF, Tomé JPC, Cavaleiro JAS, Rocha J (2012) Chem Soc Rev 41:1088–1110

    Article  Google Scholar 

  2. Banerjee R, Phan A, Wang B, Knobler C, Furukawa H, O’Keeffe M, Yaghi OM (2008) Science 319:939–943

    Article  CAS  Google Scholar 

  3. Celestian AJ, Kubicki JD, Hanson J, Clearfield A, Parise JB (2008) J Am Chem Soc 130:11689–11694

    Article  CAS  Google Scholar 

  4. Batten SR (2001) Curr Opin Solid State Mater Sci 5:107–114

    Article  CAS  Google Scholar 

  5. Pan L, Sander MB, Huang X, Li J, Smith M, Bittner E, Bockrath B, Johnson JK (2004) J Am Chem Soc 126:1308–1309

    Article  CAS  Google Scholar 

  6. Liu S, Meyers EA, Shore SG (2002) Angew Chem Int Ed 41:3609–3611

    Article  CAS  Google Scholar 

  7. Yaghi OM, Davis CE, Li GM, Li HL (1997) J Am Chem Soc 119:2861–2868

    Article  CAS  Google Scholar 

  8. Wang ZQ, Kravtsov VC, Zaworotko MJ (2005) Angew Chem Int Ed 44:2877–2880

    Article  CAS  Google Scholar 

  9. Chen MS, Chen M, Takamizawa S, Okamurm T-a, Fan J, Sun WY (2011) ChemComm 47:3787–3789

    CAS  Google Scholar 

  10. Sheldrick GM SADABS, Program for Empirical Absorption Correction of Area Detector Data, University of Göttingen, Göttingen (Germany) 2003

  11. Sheldrick GM SHELXS-97, Program for the Solution of Crystal Structures, University of Göttingen, Göttingen (Germany) 1997. See also: Sheldrick GM Acta Crystallogr. (1990) A46:467–473

  12. Sheldrick GM, SHELXL-97, Program for the Refinement of Crystal Structures, University of Göttingen, Göttingen (Germany) 1997. See also: Sheldrick GM (2008) Acta Crystallogr A64:112–122

  13. Chen MS, Bai ZS, Okamurm T-a, Su Z, Chen SS, Sun WY, Ueyama N (2010) CrystEngComm 12:1935–1944

    Article  CAS  Google Scholar 

  14. Chen MS, Bai ZS, Su Z, Chen SS, Sun WY (2009) Inorg Chem Commun 12:530–533

    Article  CAS  Google Scholar 

  15. Smith JV (1988) Chem Rev 88:149–182

    Article  CAS  Google Scholar 

  16. Chen B, Eddaoudi M, Hyde ST, O’Keeffe M, Yaghi OM (2001) Science 291:1021–1023

    Article  CAS  Google Scholar 

  17. Zhong DC, Lin JB, Lu WG, Jiang L, Lu TB (2009) Inorg Chem 48:8656–8658

    Article  CAS  Google Scholar 

  18. Liu B, Zou RQ, Zhong RQ, Han S, Shioyama H, Yamada T, Matuta G, Takeda S, Xu Q (2008) Micropor Mesopor Mater 111:470–477

    Article  CAS  Google Scholar 

  19. Zhu AX, Lin JB, Zhang JP, Chen XM (2009) Inorg Chem 48:3882–3889

    Article  CAS  Google Scholar 

Download references

Acknowledgments

The authors gratefully acknowledge the financial supports from the Key Project of Science and Technology Plan of Hunan Province (No. 2012FJ2002), the Innovation Platform Open fund of Hunan Provincial Education Department (No.11K009), the Hunan Provincial Natural Science Foundation of China (No.13JJ6069), the National Natural Science Foundation of China (No. 21102040) and the Hunan Provincial Key Discipline Construction.

Author information

Authors and Affiliations

  1. Department of Chemistry and Materials Science, Key Laboratory of Functional Organometallic Materials, Hengyang Normal University, Hengyang, 421008, Hunan, China

    Man-sheng Chen, Yi-fang Deng, Chun-hua Zhang, Jin-sheng Xu, Xue Nie & Si-ping Tang

Authors
  1. Man-sheng Chen
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Yi-fang Deng
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Chun-hua Zhang
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Jin-sheng Xu
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Xue Nie
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. Si-ping Tang
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Jin-sheng Xu.

Electronic supplementary material

Below is the link to the electronic supplementary material.

11243_2013_9744_MOESM1_ESM.doc

CCDC 874405 and 933922 contain the supplementary crystallographic data for [Ni(INAIP)(DMF)]·0.5DMF and [Ni(INAIP)(H2O)]·2H2O. These data can be obtained free of charge from The Cambridge Crystallographic Centre via www.ccdc.cam.ac.uk/data-request/cif. (DOC 381 kb)

Rights and permissions

Reprints and permissions

About this article

Cite this article

Chen, Ms., Deng, Yf., Zhang, Ch. et al. Syntheses, crystal structures and properties of two nickel(II) coordination polymers constructed from 5-(isonicotinamido)isophthalic acid. Transition Met Chem 38, 745–750 (2013). https://doi.org/10.1007/s11243-013-9744-2

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11243-013-9744-2

Keywords

Search

Navigation