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Synthesis, structure, and conformational mobility of a vaulted trans-bis(o-aminophenolato)platinum(II) complex

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Abstract

The synthesis, structure, and conformational mobility of a trans-bis(aminophenolato)platinum(II) complex bearing a dodecamethylene bridge, [Pt(L)] (1) [H 2 L = N,N′-Dimethyl-N,N′-bis(2-hydroxyphenylmethyl)dodecane-1,12-diamine] are described. The 2D NMR and X-ray diffraction analysis revealed that the complex has a “reversed U”-shaped syn conformation in the solution state, which is mainly due to steric congestion of the vaulted structure and hydrogen bonding at the bis[(o-aminomethyl)phenolato] coordination site, while the complex unit is packed in the crystalline state with “Z-shaped” anti-conformation due to highly regulated molecular arrangement by 3D CH-π and hydrogen bonding interactions.

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Acknowledgments

This work was supported by Grant-in-Aid for Scientific Research, from the Ministry of Education, Culture, Sports, Science and Technology, Japan.

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Authors and Affiliations

  1. Department of Chemistry, Graduate School of Engineering Science, Osaka University, Machikaneyama, Toyonaka, Osaka, 560-8531, Japan

    Naruyoshi Komiya, Koichi Takahashi, Tomoya Tanaka, Atsushi Yoshida & Takeshi Naota

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  1. Naruyoshi Komiya
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  2. Koichi Takahashi
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  3. Tomoya Tanaka
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  4. Atsushi Yoshida
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  5. Takeshi Naota
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Correspondence to Naruyoshi Komiya or Takeshi Naota.

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Komiya, N., Takahashi, K., Tanaka, T. et al. Synthesis, structure, and conformational mobility of a vaulted trans-bis(o-aminophenolato)platinum(II) complex. Transition Met Chem 38, 659–664 (2013). https://doi.org/10.1007/s11243-013-9734-4

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