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Syntheses, crystal structures, and magnetic and fluorescence properties of three complexes of mixed flexible N,N′-bis(3-pyridylmethyl)amine and rigid pyromellitate ligands

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Abstract

Three new complexes, {[Mn(Hbpma)2(pm)(H2O)2]·8H2O}n, {[Co(Hbpma)2(pm)(H2O)2]·8H2O}n and {[Zn(Hbpma)2(pm)(H2O)2]·8H2O}n (bpma = N,N′-bis(3-pyridylmethyl)amine and H4pm = pyromellitic acid) were synthesized and structurally characterized by single-crystal X-ray diffraction. All three complexes are isomorphous consisting of one-dimensional coordination polymers bridged by rigid pm ligands, while the flexible dipyridyl bpma only acts as a terminal ligand. The bpma ligand adopts the trans–trans conformation in all three complexes. The magnetic properties of the Mn(II) and Co(II) complexes show the occurrence of antiferromagnetic interactions between adjacent metal atoms. The Zn(II) complex exhibits fluorescent emission in the solid state at room temperature.

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Acknowledgments

This work was financially supported by the National Natural Science Foundation of China (Nos. 20901059 and 20771083) and the Technological Development Foundation Project of Tianjin Educational Committee (No. 20080503).

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Authors and Affiliations

  1. College of Chemistry, Tianjin Key Laboratory of Structure and Performance for Functional Molecule, Key Laboratory of Inorganic–Organic Hybrid Functional Material Chemistry (Ministry of Education), Tianjin Normal University, Tianjin, 300387, People’s Republic of China

    Si-Si Wang, Ping-Mei Xi, Xiu-Guang Wang, Dong-Zhao Gao, Ya-Qiu Sun, Guo-Ying Zhang & Yan-Yan Xu

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  1. Si-Si Wang
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  2. Ping-Mei Xi
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Correspondence to Dong-Zhao Gao.

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Wang, SS., Xi, PM., Wang, XG. et al. Syntheses, crystal structures, and magnetic and fluorescence properties of three complexes of mixed flexible N,N′-bis(3-pyridylmethyl)amine and rigid pyromellitate ligands. Transition Met Chem 38, 105–112 (2013). https://doi.org/10.1007/s11243-012-9666-4

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