Skip to main content
SpringerLink
Log in

Synthesis, structure and properties of a two-dimensional iron(II) metal-organic framework

  • Published:
Transition Metal Chemistry Aims and scope Submit manuscript

Abstract

Reaction of FeSO4·7H2O with 5-(isonicotinamido)isophthalic acid (H2INAIP) in the presence of NaOH results in the formation of a two-dimensional network [Fe(INAIP)(H2O)]n·2nH2O. In the complex, each INAIP2− ligand links three Fe(II) atoms to give a double-chain structure using its two carboxylate groups in μ 1–η 1:η 1 and μ 2–η 1:η 1 coordination modes. The chains are interlinked to form a layer structure through Fe–N interactions, which it is extended to a three-dimensional supramolecular structure by H-bonding interactions. The thermal and magnetic properties of the complex were investigated, and antiferromagnetic interactions were observed. Moreover, the adsorption behavior shows that the title complex has obviously selective adsorption of CO2 over N2 after the removal of the solvent molecules within the pores.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4

Similar content being viewed by others

References

  1. Celestian AJ, Kubicki JD, Hanson J, Clearfield A, Parise JB (2008) J Am Chem Soc 130:11689–11694

    Article  CAS  Google Scholar 

  2. Chen ZL, Jiang CF, Yan WH, Liang FP, Batten SR (2009) Inorg Chem 48:4674–4684

    Article  CAS  Google Scholar 

  3. Weng ZH, Chen ZL, Liang FP (2009) Inorg Chem 48:8703–8708

    Article  CAS  Google Scholar 

  4. Manos MJ, Iyer RG, Quarez E, Liao JH, Kanatzidis MG (2005) Angew Chem Int Ed 117:3618–3621

    Article  Google Scholar 

  5. Rowsell JLC, Yaghi OM (2006) J Am Chem Soc 128:1304–1315

    Article  CAS  Google Scholar 

  6. Zhang J, Chen SM, Wu T, Feng PY, Bu XH (2008) J Am Chem Soc 130:12882–12883

    Article  CAS  Google Scholar 

  7. Sun JM, Bao XH (2008) Chem Eur J 14:7478–7488

    Article  CAS  Google Scholar 

  8. Wang J, You J, Li ZS, Yang PP, Jing XY, Cao DX, Zhang ML (2008) Solid State Sci 10:1093–1098

    Article  CAS  Google Scholar 

  9. Zhang SH, Li N, Ge CM, Feng C, Ma LF (2011) Dalton Trans 40:3000–3007

    Article  CAS  Google Scholar 

  10. Serre C, Millange F, Thouvenot C, Nogués M, Marsolier G, Louёr D, Férey G (2002) J Am Chem Soc 124:13519–13526

    Article  CAS  Google Scholar 

  11. Chen JX, Ohba M, Zhao DY, Kaneko W, Kitagawa S (2006) Cryst Growth Des 6:664–668

    Article  CAS  Google Scholar 

  12. Zhu YF, Zhang LX, Schappacher FM, Pöttgen R, Shi JL, Kaskel S (2008) J Phys Chem C 112:8623–8628

    Article  CAS  Google Scholar 

  13. Chen MS, Chen M, Takamizawa S, Okamura TA, Fan J, Sun WY (2011) Chem Commun 47:3787–3789

    Article  CAS  Google Scholar 

  14. Chen MS, Bai ZS, Okamura TA, Su Z, Chen SS, Sun WY, Ueyama N (2010) Cryst Eng Commun 12:1935–1944

    CAS  Google Scholar 

  15. Chen MS, Bai ZS, Su Z, Chen SS, Sun WY (2009) Inorg Chem Commun 12:530–533

    Article  CAS  Google Scholar 

  16. Altomare A, Cascarano G, Giacovazzo C, Guagliardi A, Burla M, Polidori G, Camalli M (1994) SIR92. J Appl Crystallogr 27:435–436

    Google Scholar 

  17. Beurskens PT, Admiraal G, Beurskens G, Bosman WP, de Gelder R, Israel R (1999) Smits JMM DIRDIF99: the DIRDIF-99 Program System, technical report of the Crystallography Laboratory, University of Nijmegen, The Netherlands

  18. CRYSTALSTRUCTURE 3.8: (2000–2007) Crystal Structure Analysis Package, Rigaku and Rigaku Americas. The Woodlands, TX

  19. Cao TT, Ma Y, Zhou N, Wang C, Liao DZ, Yan SY (2010) J Coord Chem 63:988–995

    Article  CAS  Google Scholar 

  20. Chen F, Lu WM, Zhu Y, Wu B, Zheng XM (2010) J Coord Chem 63:3599–3609

    Article  CAS  Google Scholar 

  21. Wu B, Lu WM, Zheng XM (2003) J Coord Chem 56:65–70

    Article  CAS  Google Scholar 

  22. Blatov VA (2006) Multipurpose crystallochemical analysis with the program package Topos. IUCr CompComm Newsletter 7:4–38

    Google Scholar 

  23. Zhong DC, Lin JB, Lu WG, Jiang L, Lu TB (2009) Inorg Chem 48:8656–8658

    Article  CAS  Google Scholar 

  24. Choi HS, Suh MP (2009) Angew Chem Int Ed 48:6865–6870

    Article  CAS  Google Scholar 

  25. Zhu AX, Lin JB, Zhang JP, Chen XM (2009) Inorg Chem 48:3882–3889

    Article  CAS  Google Scholar 

  26. Coriani S, Halkier A, Rizzo A, Ruud K (2000) Chem Phys Lett 326:269–276

    Article  CAS  Google Scholar 

  27. Cheon YE, Suh MP (2008) Chem -Eur J 14:3961–3967

    Article  CAS  Google Scholar 

  28. Chen MS, Chen M, Okamura T-A, Sun WY, Ueyama N (2011) Micropor Mesopor Mater 139:25–30

    Article  CAS  Google Scholar 

  29. Chen MS, Tan XW, Zhang CH, Kuang DZ (2011) Z Anorg Allg Chem 637:1220–1223

    Article  CAS  Google Scholar 

  30. Riou-Cavellec M, Lesaint C, Noguès M, Grenèche JM, Férey G (2003) Inorg Chem 42:5669–5674

    Article  CAS  Google Scholar 

Download references

Acknowledgments

This work has been funded by the National Natural Science Foundation of China (21003014), Hunan Provincial Science and Technology Project (2010FJ3167), the Open Fund Project of Key Laboratories in Hunan Universities (11K009 and 10K010) and the Hunan Provincial Key Laboratory of Materials Protection for Electric Power and Transportation (No. 2012CL07), Changsha University of Science & Technology, P. R. China.

Author information

Authors and Affiliations

  1. Key Laboratory of Functional Organometallic Materials, Department of Chemistry and Materials Science, Hengyang Normal University, Hengyang, 421008, Hunan, People’s Republic of China

    Mansheng Chen, Yifang Deng, Chunhua Zhang, Zhimin Chen & Daizhi Kuang

  2. Hunan Provincial Key Laboratory of Materials Protection for Electric Power and Transportation, School of Chemistry and Biological Engineering, Changsha University of Science and Technology, Changsha, 410004, People’s Republic of China

    Mansheng Chen & Julan Zeng

Authors
  1. Mansheng Chen
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Julan Zeng
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Yifang Deng
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Chunhua Zhang
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Zhimin Chen
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. Daizhi Kuang
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding authors

Correspondence to Mansheng Chen or Julan Zeng.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Chen, M., Zeng, J., Deng, Y. et al. Synthesis, structure and properties of a two-dimensional iron(II) metal-organic framework. Transition Met Chem 37, 463–468 (2012). https://doi.org/10.1007/s11243-012-9610-7

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11243-012-9610-7

Keywords

Search

Navigation