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Hydrogen-bonded supramolecular structures constructed from trinuclear copper units

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Abstract

Four copper complexes with similar trinuclear copper units, [Cu6(Bmshp)2(SO4)2(H2O)7]·2H2O (1), [Cu3(Bmshp)(ClO4)2(H2O)4]·5H2O (2), [Cu3(Bmshp)(DMF)4(H2O)2]·H2O·2DMF·2ClO4 (3) and [Cu3(H2Bcshp)(ClO4)2(H2O)4]·3H2O (4) (H4Bmshp = 2,6-bis[(3-methoxysalicylidene)hydrazinocarbonyl]pyridine, H6Bcshp = 2,6-bis[(3-carboxylsalicylidene)hydrazinocarbonyl]pyridine), were synthesized and characterized by elemental analysis, IR and single crystal X-ray diffraction analysis. Due to the different anions, solvents and ligands used in the syntheses, complexes 1–4 exhibit diverse supramolecular structures constructed from the corresponding trinuclear copper units via H-bonds.

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References

  1. Zhao XJ, Zhang ZH, Wang Y, Du M (2007) Inorg Chim Acta 360:1921

    Article  CAS  Google Scholar 

  2. Batten SR, Robson R (1998) Angew Chem Int Ed 37:1460

    Article  Google Scholar 

  3. Zubieta J, Hagrman PJ, Hagrman D (1999) Angew Chem Int Ed 38:2638

    Article  Google Scholar 

  4. Aakeröy CB, Beatty AM, Lorimer KR (2000) J Chem Soc Dalton Trans 3869–3872

  5. Gillon AL, Lewis GR, Orpen AG, Rotter S, Starbuck J, Wang XM, Rodríguez-Martín Y, Ruiz-Pérez C (2000) J Chem Soc Dalton Trans 3897–3905

  6. Mitzi DB (2001) J Chem Soc Dalton Trans 1–12

  7. Bünzli JC, Piguet C (2002) Chem Rev 102:1897

    Article  Google Scholar 

  8. Carlucci L, Ciani G, Proserpio D (2003) Coord Chem Rev 246:247

    Article  CAS  Google Scholar 

  9. Tzeng BC, Huang YC, Chen BS, Wu WM, Lee SY, Lee GH, Peng SM (2007) Inorg Chem 46:186

    Article  CAS  Google Scholar 

  10. Han J, Yau CW, Lam CK, Mak TCW (2008) J Am Chem Soc 130:10315

    Article  CAS  Google Scholar 

  11. Wan CQ, Li GS, Chen XD, Mak TCW (2008) Cryst Growth Des 8:3897

    Article  CAS  Google Scholar 

  12. Tadokoro M, Shiomi T, Kaneyama M, Miyazato Y (2009) J Nanosci Nanotechnol 9:301

    Article  CAS  Google Scholar 

  13. Das A, Choudhury SR, Dey B, Yalamanchili SK, Helliwell M, Gamez P, Mukhopadhyay S, Estarellas C, Frontera A (2010) J Phys Chem B 114:4998

    Article  CAS  Google Scholar 

  14. Choudhury SR, Lee HM, Hsiao T-H, Colacio E, Jana AD, Mukhopadhyay S (2010) J Mol Struct 967:131

    Article  CAS  Google Scholar 

  15. Keene TD, Zimmermann I, Neels A, Sereda O, Hauser J, Liu SX, Decurtins S (2010) Cryst Growth Des 10:1854

    Article  CAS  Google Scholar 

  16. Zhang KL, Chang Y, Hou CT, Diao GW, Wu RT, Ng SW (2010) CrystEngComm 12:1194

    Article  CAS  Google Scholar 

  17. Koner R, Goldberg I (2009) CrystEngComm 11:1217

    Article  CAS  Google Scholar 

  18. Abrahams BF, Haywood MG, Robson R (2007) Polyhedron 26:300

    Article  CAS  Google Scholar 

  19. Kirillova MV, Kirillov AM, Guedes da Silva MFC, Kopylovich MN, Fraústo da Silva JJR, Pombeiro AJL (2008) Inorg Chim Acta 361:1728

    Article  CAS  Google Scholar 

  20. Adarsh NN, Kumar DK, Suresh E, Dastidar P (2010) Inorg Chim Acta 363:1367

    Article  CAS  Google Scholar 

  21. Tadokoro M, Nakasuji K (2000) Coord Chem Rev 198:205

    Article  CAS  Google Scholar 

  22. Zhao L, Xu ZQ, Thompson LK, Heath SL, Miller DO, Ohba M (2000) Angew Chem Int Ed 39:3114

    CAS  Google Scholar 

  23. Xu ZQ, Thompson LK, Miller DO (2001) Chem Commun 1170–1171

  24. Thompson LK, Zhao L, Xu ZQ, Miller DO, Reiff WM (2003) Inorg Chem 42:128

    Article  CAS  Google Scholar 

  25. Tandon SS, Dawe LN, Milway VA, Collins JL, Thompson LK (2007) Dalton Trans 1948–1953

  26. Niel V, Milway VA, Dawe LN, Grove H, Tandon SS, Abedin TSM, Kelly TL, Spencer EC, Howard JAK, Collins JL, Miller DO, Thompson LK (2008) Inorg Chem 47:176

    Article  CAS  Google Scholar 

  27. Dawe LN, Shuvaev KV, Thompson LK (2009) Chem Soc Rev 38:2334

    Article  CAS  Google Scholar 

  28. Chen XY, Zhan SZ, Meng QJ (1996) Transition Met Chem 21:345

    Article  CAS  Google Scholar 

  29. Gudasi KB, Shenoy RV, Vadavi RS, Patil MS, Patil SA (2006) J Inclusion Phenom Mol Macrocy Chem 55:93

    Google Scholar 

  30. Sheldrick GM (2008) Acta Crystallogr A64:112

    CAS  Google Scholar 

  31. van der Sluis P, Spek AL (1990) Acta Crystallogr 46:194

    Article  Google Scholar 

  32. Chen XY, Zhan SZ, Hu CJ, Meng QJ, Liu YJ (1997) J Chem Soc Dalton Trans 245–250

  33. Milway VA, Zhao L, Abedin TSM, Thompson LK, Xu ZQ (2003) Polyhedron 22:1271

    Article  CAS  Google Scholar 

  34. Zhao L, Thompson LK, Xu ZQ, Miller DO, Stirling DR (2001) J Chem Soc Dalton Trans 1706–1710

Download references

Acknowledgments

This work was supported by the National Natural Science Foundation of China (No. 20971029), Guangxi Natural Science Foundation (No. 2010GXNSFD013018 and 2010GXNSFF013001).

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Authors and Affiliations

  1. Key Laboratory for the Chemistry and Molecular Engineering of Medicinal Resources (Ministry of Education of China), School of Chemistry and Chemical Engineering, Guangxi Normal University, Guilin, 541004, China

    Su-Ni Qin, Hai-Ming Huang, Zi-Lu Chen & Fu-Pei Liang

  2. State Key Laboratory of Coordination Chemistry, Coordination Chemistry Institute, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing, 210093, China

    Su-Ni Qin

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  1. Su-Ni Qin
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  2. Hai-Ming Huang
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Correspondence to Fu-Pei Liang.

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Qin, SN., Huang, HM., Chen, ZL. et al. Hydrogen-bonded supramolecular structures constructed from trinuclear copper units. Transition Met Chem 36, 653–662 (2011). https://doi.org/10.1007/s11243-011-9515-x

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