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Tri-p-tolylphosphine-cyclopalladated ferrocenylpyrimidine complexes: synthesis, crystal structures, catalytic activity, and a palladacycle cocrystallization adduct

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Abstract

Two new tri-p-tolylphosphine-cyclopalladated ferrocenylpyrimidine complexes 1 and 2 have been prepared in good yields by reaction of the corresponding chloride-bridged palladacyclic dimers 1a and 2a with tri-p-tolylphosphine. Complexes 1 and 2 were characterized by elemental analysis, IR, 1H NMR, and ESI–MS. Additionally, their crystal structures have been determined by X-ray diffraction, and intermolecular C–H···Cl hydrogen bonds were found in their crystals. Complex 1 was found to be a palladacycle cocrystallization adduct with {PdCl2[P(C6H4-p-Me)3]2}. These complexes were found to be efficient catalysts for the Suzuki reaction.

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Acknowledgments

We are grateful to the National Natural Science Foundation of China (No. 20902043) and the Natural Science Foundation of Henan Province and Henan Education Department, China (No. 102300410220 and 2009B150019) for financial support of this work.

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Authors and Affiliations

  1. College of Chemistry and Chemical Engineering, Luoyang Normal University, Luoyang, 471022, Henan, China

    Chen Xu, Xin-Hua Lou, Zhi-Qiang Wang, Wei-Jun Fu & Bao-Ming Ji

  2. Department of Chemistry, Zhengzhou Normal University, Zhengzhou, 450044, Henan, China

    Yan-Xia Lu

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  1. Chen Xu
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Correspondence to Chen Xu.

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Xu, C., Lu, YX., Lou, XH. et al. Tri-p-tolylphosphine-cyclopalladated ferrocenylpyrimidine complexes: synthesis, crystal structures, catalytic activity, and a palladacycle cocrystallization adduct. Transition Met Chem 36, 637–642 (2011). https://doi.org/10.1007/s11243-011-9513-z

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