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Complexes of a diacetylmonoxime Schiff base of S-methyldithiocarbazate (H2damsm) with Fe(III), Ru(III)/Ru(II), and V(IV); catalytic activity and X-ray crystal structure of [Fe(Hdamsm)2]NO3·H2O

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Abstract

The complexes [M(Hdamsm)2]X·H2O (M = Fe, X = NO3; M = Ru, X = Cl), [Ru(Hdamsm)(PPh3)2X′](X′ = Cl, Br), and [VO(Hdamsm)(acac)] (H2damsm = diacetylmonoxime Schiff base of S-methyldithiocarbazate, Hacac = acetylacetone) have been prepared and characterized by spectroscopic techniques. Their redox properties were investigated by cyclic voltammetry. The X-ray crystal structure of [Fe(Hdamsm)2]NO3.H2O has been determined and shows that the complex has a distorted octahedral geometry in which the Hdamsm behaves as a monoanionic NNS tridentate ligand coordinating via oxime nitrogen, hydrazinic imine nitrogen, and thiolate sulfur. The reactivity of these complexes toward oxidation of alcohols in the presence of t-BuOOH and H2O2 as co-oxidants is reported.

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References

  1. Maurya MR, Kumar A, Bhat AR, Azam A, Bader C, Rehder D (2006) Inorg Chem 45:1260

    Article  CAS  Google Scholar 

  2. Maurya MR, Khurara S, Shailendra, Azam A, Zhang W, Rehder D (2003) Eur J Inorg Chem 1966

  3. Hamid MHS, Ali MA, Mirza AH, Bernhardt PV, Moubaraki B, Murry KS (2009) Inorg Chim Acta 362:3648, and references therein

  4. Maurya MR, Khurana S, Zhang W, Rehder D (2002) Eur J Inorg Chem 1749

  5. Salem NMH, El-Sayed L, Iskander MF (2008) Polyhedron 27:3215

    Article  CAS  Google Scholar 

  6. Chumakov YM, Biyushkin VN (1982) Zh Strukt Khim 23:175

    CAS  Google Scholar 

  7. Wolkert WA, Hoffman TJ (1999) Chem Rev 99:2269

    Article  Google Scholar 

  8. Moszner M, Trzeciak AM, Ziolkowski JJ (1998) J Mol Catal A 130:241

    Article  CAS  Google Scholar 

  9. Tavagnacco C, Moszner M, Cozzi S, Peressini S, Costa G (1998) J Electroanal Chem 448:41

    Article  CAS  Google Scholar 

  10. Elsayed SA, El-Hendawy AM, Mostafa SI, Butler IS (2010) Inorg Chem Acta 363:2526

    Article  CAS  Google Scholar 

  11. Elsayed SA, El-Hendawy AM, Mostafa SI, Jean-Claude BJ, Todorova M, Butler IS (2010) Bioinorg Chem Appl 2010:149149

    Article  Google Scholar 

  12. El-Hendawy AM, Al-Kubaisi AH, Al-Madfa HA (1997) Polyhedron 16:3039

    Article  CAS  Google Scholar 

  13. El-Hendawy AM, Alqaradawi SY, Al-Madfa HA (2000) Transition Met Chem 25:572

    Article  CAS  Google Scholar 

  14. Mackay S, Gilmore C, Edwards CJ, Stewart N, Shankland K (1999) maXus computer program for the solution and refinement of crystal structures. Bruker Nonius, The Netherlands. MacScience, Japan and The University of Glasgow

    Google Scholar 

  15. Altomare A, Cascarano G, Giacovazzo C, Guagliardi A, Burla MC, Polidori G, Camalli M (1994) J Appl Cryst 27:435

    Google Scholar 

  16. Otwinowski Z, Minor W (1997). Methods in Enzymology, 276. In: Carter Jr CW, Sweet RM (ed). Academic Press, New York, pp 307–326

  17. Das M, Livingstone SE (1976) Inorg Chim Acta 19:5

    Article  CAS  Google Scholar 

  18. Stephenson TA, Wilkinson G (1966) J Inorg Nucl Chem 28:945

    Article  CAS  Google Scholar 

  19. Rowe RA, Jones MM (1957) Inorg Synth 5:113

    Article  CAS  Google Scholar 

  20. Sreekanth A, Kurup MRP (2004) Polyhedron 23:969

    Article  CAS  Google Scholar 

  21. Choi K-Y, Yang S-M, Lee K-C, Ryu H, Lee CH, Seo J, Suh M (2008) Transit Met Chem 33:99

    Article  CAS  Google Scholar 

  22. Tido EWY, Alberda van Ekenstein GOR, Meetsma A, van Koningsbruggen PJ (2008) Inorg Chem 47:147

    Google Scholar 

  23. Katti KV, Singh PR, Barnes CL (1993) J Chem Soc Dalton Trans 2153–2156

  24. Timken MD, Wilson SR, Hendrickson DN (1985) Inorg Chem 24:3450

    Article  CAS  Google Scholar 

  25. Garcia-Tojal J, Pizarro JL, Lezama L, Arriortua MI, Rojo T (1998) Inorg Chim Acta 278:150

    Article  CAS  Google Scholar 

  26. Kannappan R, Tanase S, Mutikainen I, Turpeinen U, Reedijk J (2006) Polyhedron 25:1646

    Article  CAS  Google Scholar 

  27. Graminha AE, Vilhena FS, Batista AA, Louro SRW, Ziolli RL, Teixeira LR, Beraldo H (2008) Polyhedron 27:547

    Article  CAS  Google Scholar 

  28. Bera P, Baek IC, Seok SI, Saha N (2009) Russian J Coord Chem 35:526

    Article  CAS  Google Scholar 

  29. Medhi OK, Agarwala U (1980) J Inorg Nucl Chem 1413

  30. Floquet S, Munoz MC, Guillot R, Riviere E, Blain G, Real J-A, Biollot M-L (2009) Inorg Chim Acta 362:56

    Article  CAS  Google Scholar 

  31. Maia PI da S, Pavan FR, Leite CQF, Lemos SS, de Sousa GF, Batista AA, Nascimento OR, Ellena J, Castellano EE, Niquet E, Deflon VM (2009) Polyhedron 28:398 and references therein

  32. Chitrapriya N, Mahalingam V, Channels LC, Zeller M, Fronczek FR, Natarajan K (2008) Inorg Chim Acta 361:2841

    Article  CAS  Google Scholar 

  33. Moszner M, Kubiak M, Ziolkowski JJ (2004) Inorg Chim Acta 357:115

    Article  CAS  Google Scholar 

  34. Ghatak N, Bhattacharya S (1996) Transit Met Chem 21:158

    Article  CAS  Google Scholar 

  35. Lobana TS, Bawa G, Butcher RJ, Liaw B-J, Liu CW(2006) Polyhedron 25:2897

    Google Scholar 

  36. El-Hendawy AM, El-Kourashy AE, Shanab MM (1992) Polyhedron 11:523

    Article  CAS  Google Scholar 

  37. Hawkins CJ, Kabanos TA (1989) Inorg Chem 28:1084

    Article  CAS  Google Scholar 

  38. El-Hendawy AM (1991) Polyhedron 10:2511

    Article  CAS  Google Scholar 

  39. Sengupta P, Dinda R, Gosh S, Sheldrick WS (2003) Polyhedron 22:447

    Article  CAS  Google Scholar 

  40. Mondal B, Drew MGB, Ghosh T (2009) Inorg Chim Acta 362:3303

    Article  CAS  Google Scholar 

  41. Mizushima K, Nakaura M, Park S-B, Nishiyama H, Monjushiro H, Harada K, M-aki Haga (1997) Inorg Chim Acta 261:175

    Article  CAS  Google Scholar 

  42. Barak G, Dakka J, Sasson Y (1988) J Org Chem 53:3553

    Article  CAS  Google Scholar 

  43. Lau TC, Che CM, Lee WO, Poon CK (1988) J Chem Soc Chem Commun 1406

  44. Faraj M, Hill CL (1987) J Chem Soc Chem Commun 1487

  45. Martin SE, Garrone A (2003) Tetrahedron Lett 44:549

    Article  CAS  Google Scholar 

  46. Zeng W, Ballard TE, Melander C (2006) Tetrahedron Lett 47:5923

    Article  CAS  Google Scholar 

  47. Goldstein AS, Beer RH, Drago RS (1994) J Am Chem Soc 116:2424

    Article  CAS  Google Scholar 

  48. Barton DHR, Beviere SD, Chabot BM, Chavasiri W, Taylor DK (1994) Tetrahedron Lett 35:4681

    Article  CAS  Google Scholar 

  49. Butler A, Clague MJ, Meister GE (1994) Chem Rev 94:625

    Article  CAS  Google Scholar 

  50. Maurya MR, Khurana S, Zhang W, Rehder D (2002) J Chem Soc Dalton Trans 3015

  51. Suss-Fink G, Stanis Las S, Shulpin GB, Nizova GV (2000) Appl Organomet Chem 14:623

    Article  CAS  Google Scholar 

  52. Figiel PJ, Sobczak JM (2009) J Catal 263:167

    Article  CAS  Google Scholar 

Download references

Acknowledgments

We thank Mansoura University for a grant to one of us (A. M. F) and also National Research Centre in Cairo for the X-ray crystallographic facility.

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Authors and Affiliations

  1. Chemistry Department, Faculty of Science, Mansoura University, Damietta, Egypt

    Ahmed M. El-Hendawy, Ahmed M. Fayed & Mohamed R. Mostafa

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  1. Ahmed M. El-Hendawy
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  2. Ahmed M. Fayed
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  3. Mohamed R. Mostafa
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Corresponding author

Correspondence to Ahmed M. El-Hendawy.

Additional information

This paper is dedicated to Professor William (Bill) P. Griffith, for his many contributions in coordination chemistry and homogenous catalysis.

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El-Hendawy, A.M., Fayed, A.M. & Mostafa, M.R. Complexes of a diacetylmonoxime Schiff base of S-methyldithiocarbazate (H2damsm) with Fe(III), Ru(III)/Ru(II), and V(IV); catalytic activity and X-ray crystal structure of [Fe(Hdamsm)2]NO3·H2O. Transition Met Chem 36, 351–361 (2011). https://doi.org/10.1007/s11243-011-9477-z

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