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Palladium(II) complexes with R2edda-derived ligands. Part V. Reaction of O,O′-diethyl-(S,S)-ethylenediamine-N,N′-di-2-(3-methyl)butanoate with K2[PdCl4]

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Abstract

The reaction of K2[PdCl4] with [(S,S)-H2(Et)2eddv]Cl2 diester (O,O′-diethyl-(S,S)-ethylenediamine-N,N′-di-2-(3-methyl)butanoate) (1) resulted in [PdCl2{(S,S)-(Et)eddv-κ2 N,N′,κO}] (2) complex with one hydrolyzed ester group. The compound was characterized by spectroscopic methods and it was found that the reaction is diastereoselective (1H and 13C NMR; one diastereoisomer of four possible). In addition, the structure of 2 was confirmed by X-ray diffraction analysis, indicating that the product is the (R,R)–N,N′-configured isomer. DFT calculations support the formation of one diastereoisomer of 2.

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Acknowledgments

The authors are grateful to the Ministry of Science and Environmental Protection of the Republic of Serbia for financial support (Grant No. 172016).

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, University of Kragujevac, R. Domanovića 12, 34000, Kragujevac, Serbia

    Gordana P. Radić, Verica V. Glođović & Srećko R. Trifunović

  2. Institut für Chemie, Martin-Luther-Universität Halle-Wittenberg, Kurt-Mothes-Straβe 2, 06120, Halle, Germany

    Goran N. Kaluđerović

  3. Biozentrum, Martin-Luther-Universität Halle-Wittenberg, Weinbergweg 22, 06120, Halle, Germany

    Goran N. Kaluđerović

  4. Department of Chemistry and Pharmacy, Inorganic Chemistry, Universität Erlangen-Nürnberg, Egerlandstrasse 1, 91058, Erlangen, Germany

    Frank W. Heinemann

Authors
  1. Gordana P. Radić
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  2. Verica V. Glođović
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  3. Goran N. Kaluđerović
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  4. Frank W. Heinemann
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  5. Srećko R. Trifunović
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Correspondence to Goran N. Kaluđerović or Srećko R. Trifunović.

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Radić, G.P., Glođović, V.V., Kaluđerović, G.N. et al. Palladium(II) complexes with R2edda-derived ligands. Part V. Reaction of O,O′-diethyl-(S,S)-ethylenediamine-N,N′-di-2-(3-methyl)butanoate with K2[PdCl4]. Transition Met Chem 36, 331–336 (2011). https://doi.org/10.1007/s11243-011-9473-3

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  • DOI: https://doi.org/10.1007/s11243-011-9473-3

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