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Palladium tetrazole–supported complex as an efficient catalyst for the Heck reaction

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Abstract

A tetrazole-supported polymeric ligand has been synthesized. The palladium complex derived from the polymeric material has been evaluated as a catalyst for the Heck reaction of aryl iodides and bromides with styrene to provide the corresponding products in high yields. The reaction proceeded smoothly in the presence of 1 mol% with respect to Pd of catalyst in DMF at 125 or 140 °C within 1–3 h. Recycling studies showed that the catalyst can be readily recovered and reused for several times without significant loss of catalytic activity.

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Authors and Affiliations

  1. Chemical Engineering College, Nanjing University of Science & Technology, 210094, Nanjing, People’s Republic of China

    Ying He & Chun Cai

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  1. Ying He
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  2. Chun Cai
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Correspondence to Chun Cai.

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He, Y., Cai, C. Palladium tetrazole–supported complex as an efficient catalyst for the Heck reaction. Transition Met Chem 36, 113–117 (2011). https://doi.org/10.1007/s11243-010-9442-2

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  • DOI: https://doi.org/10.1007/s11243-010-9442-2

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