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Design and characterization of silver(I) azide coordination polymers based on 1,2-bis(4-pyridyl)ethane and phenazine

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Abstract

Two silver(I) azide supramolecular coordination polymers (SCPs) with N-donor ligands have been synthesized and structurally characterized by physicochemical and spectroscopic methods; [AgN3.bpe] where bpe = 1,2-bis(4-pyridyl)ethane, 1, and [(AgN3)2.phenz], 2, where phenz = phenazine. Syntheses were carried out in H2O/acetonitrile/NH3 media at room temperature. The topology of the bipodal ligands directs the silver azide building blocks to adopt different structures; 1D-chain, 1, or 1D-ribbon, 2. The azide groups exhibit an unusual bent structure with increasing bridging capability to adopt enough space for the bipodal ligands. The structure of SCP 2 contains the cyclic motif {Ag2(μ3-N3)2} to accommodate the voluminous phenz ligand. The emission spectra of the SCPs 1 and 2 display emission bands at 400–650 nm.

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Authors and Affiliations

  1. Chemistry Department, Faculty of Science, Tanta University, Tanta, Egypt

    Safaa El-din H. Etaiw & Ahmed S. Badr El-din

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  1. Safaa El-din H. Etaiw
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  2. Ahmed S. Badr El-din
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Correspondence to Safaa El-din H. Etaiw.

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Etaiw, S.Ed.H., Badr El-din, A.S. Design and characterization of silver(I) azide coordination polymers based on 1,2-bis(4-pyridyl)ethane and phenazine. Transition Met Chem 36, 13–19 (2011). https://doi.org/10.1007/s11243-010-9428-0

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