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Styrene-hydroxyethyl methacrylate copolymer-supported porphyrinatomanganese(III) complexes: synthesis and catalytic cyclohexane hydroxylation with molecular oxygen

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Abstract

Two new styrene-hydroxyethyl methacrylate copolymers containing immobilized porphyrinatomanganese(III) were prepared and characterized as microspheres by SEM, UV–Vis, FT-IR, and TG-DTG. Their catalytic activities have been investigated for the hydroxylation of cyclohexane in the presence of molecular oxygen under mild conditions. The copolymer microspheres proved to be more efficient catalysts than the corresponding non-supported porphyrinatomanganese(III) complex. The alkylated polymer microspheres with porphyrinatomanganese(III) had the highest catalytic activity, which may be attributable to the hydrophobic microenvironment around the porphyrinatomanganese(III) centers, resulting from the alkyl groups.

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Acknowledgments

We are grateful to the supports of Guangzhou Municipality Science & Technology Bureau of China, the National Natural Science Foundation of China, and National Key Foundation Research Development Project (973) Item of China (No. 2007 CB815306).

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Authors and Affiliations

  1. MOE Key Laboratory of Bioinorganic and Synthetic Chemistry, School of Chemistry and Chemical Engineering & State Key Laboratory of Optoelectronic Material and Technologies, Sun Yat-Sen University, 510275, Guangzhou, People’s Republic of China

    Yuan-Jian Ye, Jin-Wang Huang, Jin-Hua Cai, Han-Cheng Yu, Wen-Hai Wu, Xian-Tai Zhou, Hong-Bin Ji & Liang-Nian Ji

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  1. Yuan-Jian Ye
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  2. Jin-Wang Huang
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  3. Jin-Hua Cai
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Correspondence to Jin-Wang Huang.

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Ye, YJ., Huang, JW., Cai, JH. et al. Styrene-hydroxyethyl methacrylate copolymer-supported porphyrinatomanganese(III) complexes: synthesis and catalytic cyclohexane hydroxylation with molecular oxygen. Transition Met Chem 35, 627–632 (2010). https://doi.org/10.1007/s11243-010-9373-y

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