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Synthesis, characterization and catalytic activities of a reusable polymer-anchored palladium(II) complex: effective catalytic hydrogenation of various organic substrates

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Abstract

A poly(3,6-dibenzaldimino N-vinyl carbazole) Pd(II) complex has been synthesized and characterized by physicochemical and spectroscopic techniques. The complex was found to be highly active toward hydrogenation reactions of various organic substrates under atmospheric pressure at ambient temperature. A tentative reaction mechanism is proposed on the basis of kinetic studies and isolation of reactive intermediates. The catalyst shows good conversion rates, thermal stability and recyclability.

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Acknowledgments

We thank the Department of Chemistry, University of Calcutta, for providing the instrumental support. One of the authors, K.T., is thankful to the University Grants Commission (Eastern Region), India, for financial support. We acknowledge DST, CSIR and UGC, New Delhi, India, for financial supports.

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Authors and Affiliations

  1. Department of Chemistry, University of Kalyani, Kalyani, Nadia, 741235, WB, India

    Manirul Islam, Paramita Mondal & Anupam Singha Roy

  2. Department of Chemistry, B.S. College, S-24 P.G.S., Canning, 743329, WB, India

    Kazi Tuhina

Authors
  1. Manirul Islam
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  2. Paramita Mondal
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  3. Anupam Singha Roy
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  4. Kazi Tuhina
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Correspondence to Manirul Islam.

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Islam, M., Mondal, P., Roy, A.S. et al. Synthesis, characterization and catalytic activities of a reusable polymer-anchored palladium(II) complex: effective catalytic hydrogenation of various organic substrates. Transition Met Chem 35, 427–435 (2010). https://doi.org/10.1007/s11243-010-9345-2

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  • DOI: https://doi.org/10.1007/s11243-010-9345-2

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