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Nickel(II) complexes of 5-phenyl and 5-furan-1,3,4-oxadiazole-2-thiones containing ethylenediamine: synthesis, spectral and X-ray characterization

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Abstract

The products obtained by the reactions of Ni(OAc)2·4H2O with Hpot (Hpot = 5-phenyl-1,3,4-oxadiazole-2-thione) and [K(H2fchc)] (potassium N′-(furan-2-carbonyl) hydrazine carbodithioate), on treatment with excess of ethylenediamine (en), gave mixed ligand complexes [Ni(pot)2(en)2] (1) and [Ni(fot)2(en)2] (2) (fot = 5-furan-(1,3,4)-oxadiazole-2-thione). These complexes have been characterized with the aid of elemental analyses, IR, magnetic susceptibility and single crystal X-ray studies. In both complexes, the heterocyclic ligand coordinates through oxadiazole nitrogen, and the ligand exists as the thione form. The complexes 1 and 2 have distorted octahedral geometries around the centrosymmetric Ni(II) center with trans oxadiazole ligands. Both complexes show extended hydrogen bonding to give a supramolecular framework.

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Acknowledgments

Authors thank CSIR, New Delhi for financial support by grant No. 01 (2152)07/EMR-II.

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Authors and Affiliations

  1. Department of Chemistry, Banaras Hindu University, Varanasi, 221005, India

    Nand K. Singh, Manoj K. Bharty & Surendra K. Kushawaha

  2. Department of Chemistry, Howard University, Washington, DC, 20059, USA

    Raymond J. Butcher

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  1. Nand K. Singh
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  2. Manoj K. Bharty
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Correspondence to Nand K. Singh.

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Singh, N.K., Bharty, M.K., Kushawaha, S.K. et al. Nickel(II) complexes of 5-phenyl and 5-furan-1,3,4-oxadiazole-2-thiones containing ethylenediamine: synthesis, spectral and X-ray characterization. Transition Met Chem 35, 205–211 (2010). https://doi.org/10.1007/s11243-009-9315-8

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