Abstract
Microwave-assisted synthesis of secondary and tertiary ferrocenylamines is achieved by using an amine exchange reaction between ferrocenylmethyltrimethyl ammonium iodide and aryl amines in aqueous hydrotropic solution. The synthesis proceeds in excellent yields within short reaction times.
Similar content being viewed by others
References
Kealy TJ, Pauson PL (1951) Nature 168:1039
Miller SA, Tebboth JA, Tremaine JF (1952) J Chem Soc 632
Colacot TJ (2003) Chem Rev 103:3101
Kaifer AE, de Mendoza J (1996) Comprehensive supramolecular chemistry, Vol 1. Oxford, Elsevier
Yao T, Rechnitz GA (1987) Biosensors 3:307
Kopf-Maier P, Kopf H (1987) Chem Rev 87:1137
Biot C, Delhaes L, N’Diaye CM, Maciejewski LA, Camus D, Dive D (1999) Bioorg Med Chem 7:2843
Epton R, Marr G, Rogers GK (1976) J Organomet Chem 10:C42
Zhu H, Lin H, Guo H, Yu L (2007) Mat Sci Eng B 138:101
Togni A, Hayashi T (1995) Ferrocenes: homogeneous catalysis/organic synthesis/material science. Wiley–VCH, Weinheim
Gruter GM, van Klink GPM, Akkerman OS, Bickelhanpt F (1995) Chem Rev 95:2405
Oame I (1988) Coord Chem Rev 83:137
Ryabov AD (1990) Chem Rev 90:403
Wang HX, Li YJ, Jin R, Niu JR, Wu HF, Zhou HC, Xu J, Gao RQ, Geng FY (2006) J Organomet Chem 691:987 and references therein
Wang HX, Ding L, Wu YJ (2003) J Organomet Chem 679:130
Rashinkar G, Pore S, Salunkhe R (2009) Phosphorus Sulfur Silicon Relat Elem 184:1750
Khadilkar BM, Sadvilkar VG, Gaikar VG (1995) J Chem Technol Biotechnol 63:33
Khadilkar BM, Gaikar VG, Chitnavis AA (1995) Tetrahedron Lett 36:8083
Laxman M, Sharma MM (1990) Synth Commun 20:111
Khadilkar BM, Madyar VR (2001) Org Process Res Dev 4:452
Lindsay JK, Hauser CR (1957) J Org Chem 22:355
Furnis BS, Hannaford AJ, Smith PWG, Tatchell AR (1996) Vogel’s textbook of practical organic chemistry. Prentice Hall
Gao Y, Twamley B, Shreeve JM (2004) Inorg Chem 43:3406
Khrushcheva NS (2003) Russ Chem Bull 52:2146
Bildstein B, Malaun M, Kopacka H, Ongania KH, Wurst K (1998) J Organomet Chem 552:45
Dallinger D, Kappe CO (2007) Chem Rev 107:2563
Acknowledgments
We gratefully acknowledge the financial support from the Department of Science Technology and University Grants Commission for FIST and SAP, respectively.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Rashinkar, G., Kamble, S., Kumbhar, A. et al. Facile synthesis of ferrocenylamines in aqueous hydrotropic solution using microwaves. Transition Met Chem 35, 185–190 (2010). https://doi.org/10.1007/s11243-009-9312-y
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11243-009-9312-y