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Formation of polymeric chain assemblies of transition metal complexes with a multidentate Schiff-base

Transition Metal Chemistry volume 34, pages 593–598 (2009)Cite this article

Abstract

The new multidentate Schiff-base (E)-6,6′-((1E,1′E)-(ethane-1,2-diylbis(azan-1-yl-1-ylidene))bis(methan-1-yl-ylidene))bis(4-methyl-2-((E)(pyridine-2-ylmethylimino)methyl)phenol) H2L and its polymeric binuclear metal complexes with Cr(III), Mn(II), Fe(II), Co(II), Ni(II), Cu(II), Zn(II), Cd(II) and Hg(II) are reported. The reaction of 2,6-diformyl-4-methyl-phenol with ethylenediamine in mole ratios of 2:1 gave the precursor 3,3′-(1E,1′E)-(ethane-1,2-diylbis(azan-1-yl-1ylidene))bis(methan-1-yl-1-ylidene)bis(2-hydroxy-5-methylbenzaldehyde) W. Condensation of the precursor with 2-(amino-methyl)pyridine in mole ratios of 1:2 gave the new N6O2 multidentate Schiff-base ligand H2L. Upon complex formation, the ligand behaves as a dibasic octadentate species with the involvement of the nitrogen atoms of the pyridine groups in coordination for all complexes. The mode of bonding and overall geometry of the complexes were determined through physico-chemical and spectroscopic methods. These studies revealed octahedral geometries for Cr(III), Mn(II), Fe(II), Co(II), Ni(II), Cu(II), Cd(II) and Hg(II) complexes of general formulae [Cr III2 (L)Cl2]Cl2, [Ni II2 (L)(H2O)2]Cl2 and [M2(L)Cl2] and five co-ordinate Zn(II) complex of general formula [Zn II2 (L)]Cl2.

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Scheme 1
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References

  1. Lehn JM (1995) Supramolecular chemistry concepts and perspectives, 1st edn. Wiley-VCH, Weinheim

    Google Scholar 

  2. Belghoul B, Welterlich W, Maier A, Toutianoush A, Rabindranath AR, Tieke B (2007) Langmuir 23:5062. doi:10.1021/la062044c

    Article  CAS  Google Scholar 

  3. Kurmoo M, Kumagai H, Akita-Tanaka M, Inoue K, Takagi S (2006) Inorg Chem 45:1627. doi:10.1021/ic051633n

    Article  CAS  Google Scholar 

  4. Dickie DA, Schatte G, Jennings MC, Jenkins HA, Khoo SYL, Clyburne JAC (2006) Inorg Chem 45:1646. doi:10.1021/ic051690g

    Article  CAS  Google Scholar 

  5. Barton TJ, Bull LM, Klemperer WG, Loy DA, McEnaney B, Misono M, Monson PA, Pez G, Scherer GW, Vartuli JC, Yaghi OM (1999) Chem Mater 11:2633. doi:10.1021/cm9805929

    Article  CAS  Google Scholar 

  6. Andruh M (2005) Pure Appl Chem 77:1685. doi:10.1351/pac200577101685

    Article  CAS  Google Scholar 

  7. Elermany Y, Kara H, Elmali A (2003) Z Naturforsch 58a:363

    Google Scholar 

  8. Al-Jeboori MJ, Al-Shihri AS (2000) J Saudi Chem Soc 5:341

    Google Scholar 

  9. Al-Jeboori MJ, Kashta AA (2004) Mu’Tahlil-Buhuth Wadirasat 19:89

    Google Scholar 

  10. Costamagna J, Ferraudi G, Matsuhiro B, Vallette MC, Canales J, Villagra’n M, Vargas J, Aguirre MJ (2000) Coord Chem Rev 196:125. doi:10.1016/S0010-8545(99)00165-4

    Article  CAS  Google Scholar 

  11. Coughlin PK, Lippard SJ (1984) J Am Chem Soc 106:2328. doi:10.1021/ja00320a018

    Article  CAS  Google Scholar 

  12. Januszko A, Kaszynski P, Grüner B (2007) Inorg Chem 46:6078. doi:10.1021/ic7005937

    Article  CAS  Google Scholar 

  13. Katsuki T (1995) Coord Chem Rev 140:189. doi:10.1016/0010-8545(94)01124-T

    Article  CAS  Google Scholar 

  14. Samsel EG, Srinivasan K, Kochi JK (1985) J Am Chem Soc 107:7606. doi:10.1021/ja00311a064

    Article  CAS  Google Scholar 

  15. Al-Jeboori MJ, Al-Dujaili AH, Al-Janabi AE (2009) Transit Met Chem 34:109. doi:10.1007/s11243-008-9165-9

    Article  CAS  Google Scholar 

  16. Verani CN, Rentschler L, Thomas W, Bill E, Chaudhuri P (2000) J Chem Soc Dalton Trans 251. doi:10.1039/a908426f

  17. Geary WJ (1971) Coord Chem Rev 7:81. doi:10.1016/S0010-8545(00)80009-0

    Article  CAS  Google Scholar 

  18. Saravanakumar D, Sengottuvelan N, Priyadarshni G, Kandaswamy M, Okawa H (2004) Polyhedron 23:665. doi:10.1016/j.poly.2003.11.004

    Article  CAS  Google Scholar 

  19. Livingston SE, Mayfield JH, Moorse DS (1975) Aust J Chem 28:2531. doi:10.1071/CH9752531

    Article  Google Scholar 

  20. El-Sonbati AZ, El-bindary AA, Al-Sarawy AA (2002) Spectrochim Acta Part A 58:2771. doi:10.1016/S1386-1425(02)00021-5

    Article  CAS  Google Scholar 

  21. Sreedaran S, Bharathi KS, Rahiman AK, Rajesh K, Nirmala G, Jagadish L, Kaviyarasan V, Narayanan V (2008) Polyhedron 27:1867. doi:10.1016/j.poly.2008.02.022

    Article  CAS  Google Scholar 

  22. Sreedaran S, Bharathi KS, Rahiman AK, Jagadish L, Kaviyarasan V, Narayanan V (2008) Polyhedron 27:2931. doi:10.1016/j.poly.2008.06.025

    Article  CAS  Google Scholar 

  23. Nakamoto K, Ohkaku N (1971) Inorg Chem 10:798. doi:10.1021/ic50098a027

    Article  CAS  Google Scholar 

  24. Ahsen V, Gök F, Bekaroğlu Ö (1987) J Chem Soc Dalton Trans 1827. doi:10.1039/dt9870001827

  25. Lever ABP (1984) Inorganic electronic spectroscopy, 2nd edn. Elesvier, New York

    Google Scholar 

  26. Figgis BN (1966) Introduction to ligand field. Inter science publisher, Wiley, New York

    Google Scholar 

  27. Sutton D (1969) Electronic spectra of transition metal complex, 1st edn. McGraw–Hill publ. Co. Ltd, New York

    Google Scholar 

  28. Chandra S, Pundir M (2008) Spectrochim Acta Part A 69:1. doi:10.1016/j.saa.2007.02.019

    Article  Google Scholar 

  29. Modi CK (2009) Spectrochim Acta Part A 71:1741. doi:10.1016/j.saa.2008.06.024

    Article  CAS  Google Scholar 

  30. Okawa H, Tadokora M, Aratake TY, Ohba M, Shindom K, Mitsumi M, Koikawa M, Tomono M, Fenton DE (1993) J Chem Soc Dalton Trans 253. doi:10.1039/dt9930000253

  31. Jin Y, Yoon I, Seo J, Lee J-E, Moon S-T, Kim J, Han SW, Park K-M, Lindoy LF, Lee SS (2005) Dalton Trans 788. doi:10.1039/b415794j

  32. Mareque-Rivas JC, Prabaharan R, Parsons S (2004) Dalton Trans 1648. doi:10.1039/b402084g

  33. Huang W, Gou S, Hu D, Chantrapromma S, Fun H-K, Meng Q (2002) Inorg Chem 41:864. doi:10.1021/ic010407k

    Article  CAS  Google Scholar 

Download references

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Authors and Affiliations

  1. Department of Chemistry, College of Education, Ibn Al-Haitham, University of Baghdad, P.O. Box 4150, Adamiyah, Baghdad, Iraq

    Mohamad Jaber Al-Jeboori, Hasan Ahmad Hasan & Worood A. Jaafer Al-Sa’idy

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  1. Mohamad Jaber Al-Jeboori
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  2. Hasan Ahmad Hasan
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  3. Worood A. Jaafer Al-Sa’idy
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Correspondence to Mohamad Jaber Al-Jeboori.

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Al-Jeboori, M.J., Hasan, H.A. & Jaafer Al-Sa’idy, W.A. Formation of polymeric chain assemblies of transition metal complexes with a multidentate Schiff-base. Transition Met Chem 34, 593–598 (2009). https://doi.org/10.1007/s11243-009-9235-7

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  • DOI: https://doi.org/10.1007/s11243-009-9235-7

Keywords

  • Electronic Spectrum
  • Polymeric Complex
  • Fast Atom Bombardment
  • Hydroformylation
  • Octahedral Geometry