Skip to main content
SpringerLink
Log in

Complexes of podand-containing bis(dithiophosphonate) ligands with cobalt(II), nickel(II) and cadmium(II): recognition of CH2Cl2

  • Published:
Transition Metal Chemistry Aims and scope Submit manuscript

    We’re sorry, something doesn't seem to be working properly.

    Please try refreshing the page. If that doesn't work, please contact support so we can address the problem.

Abstract

Reaction of the potassium salts of podand-containing bis(dithiophosphonate)s [PhO(4-C6H4)P(S)(SH)OCH2CH2]2O (H 2 L) with Co(II), Ni(II) and Cd(II) in aqueous EtOH leads to complexes of formulae M2(L-S,S′)2. The structural formulae of the compounds were deduced by physico-chemical and spectroscopic methods. It was established that complex Ni 2 L 2 recognizes CH2Cl2.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Scheme 1
Chart 1
Fig. 1

Similar content being viewed by others

References

  1. Zazybin A, Osipova O, Khusnutdinova U, Aristov I, Solomonov B, Sokolov F, Babashkina M, Zabirov N (2006) J Mol Catal A: Chem 253:234. doi:10.1016/j.molcata.2006.03.033

    Article  CAS  Google Scholar 

  2. Guttmann M, Lubert KH, Beyer L (2006) J Anal Chem 356:263

    Google Scholar 

  3. Guillon E, Mohamadou G, Déchamps-Olivier I, Barbier JP (1996) Polyhedron 15:947. doi:10.1016/0277-5387(95)00305-6

    Article  CAS  Google Scholar 

  4. Mohamadou A, Déchamps-Olivier I, Barbier JP (1994) Polyhedron 13:3277. doi:10.1016/S0277-5387(00)83108-3

    Article  CAS  Google Scholar 

  5. Déchamps-Olivier I, Guillon E, Mohamadou A, Barbier JP (1996) Polyhedron 15:3617. doi:10.1016/0277-5387(96)00081-2

    Article  Google Scholar 

  6. van Vegel FCJM, Verboom W, Reinhoudt DN (1994) Chem Rev 94:279. doi:10.1021/cr00026a001

    Article  Google Scholar 

  7. Verat AYu, Sokolov FD, Zabirov NG, Babashkina MG, Krivolapov DB, Brusko VV, Litvinov IA (2006) Inorg Chim Acta 359:475

    Article  CAS  Google Scholar 

  8. Haiduc I, Sowerby DB, Lu S-F (1995) Polyhedron 14:3389. doi:10.1016/0277-5387(95)00108-5

    Article  CAS  Google Scholar 

  9. Haiduc I (2001) J Organomet Chem 623:29. doi:10.1016/S0022-328X(00)00677-X

    Article  CAS  Google Scholar 

  10. Nasirov FA (2001) Neftekhimiya 41:403

    CAS  Google Scholar 

  11. Kuchen W, Hertel H (1969) Angew Chem Int Ed 8:89. doi:10.1002/anie.196900891

    Article  CAS  Google Scholar 

  12. Takahashi Y, Yuki R, Sugiura M, Motojima S, Sugiyama K (1980) J Cryst Growth 50:491. doi:10.1016/0022-0248(80)90098-6

    Article  CAS  Google Scholar 

  13. Byrom C, Malik MA, O’Brien P, White AJP, Williams DJ (2000) Polyhedron 19:211. doi:10.1016/S0277-5387(99)00352-6

    Article  CAS  Google Scholar 

  14. Mikulec J, Černý Č (1987) Spectrochim Acta 43A:849

    CAS  Google Scholar 

  15. Davison A, Switkes ES (1971) Inorg Chem 10:837. doi:10.1021/ic50098a034

    Article  CAS  Google Scholar 

  16. Simón-Manso E, Valderrama M, Boys D (2001) Inorg Chem 40:3647. doi:10.1021/ic001184l

    Article  CAS  Google Scholar 

  17. Levesanos N, Robertson SD, Maganas D, Raptopoulou CP, Terzis A, Kyritsis P, Chivers T (2008) Inorg Chem 47:2949. doi:10.1021/ic800272v

    Article  CAS  Google Scholar 

Download references

Acknowledgements

This work was supported by the joint program of CRDF and the Russian Ministry of Education and Science (BHRE 2008 Y5-C-07-09), Russian Science Support Foundation.

Author information

Authors and Affiliations

  1. A. M. Butlerov Chemistry Institute, Kazan State University, Kremlevskaya St. 18, 420008, Kazan, Russian Federation

    Alphia R. Gataulina, Damir A. Safin, Timur R. Gimadiev & Marina V. Pinus

Authors
  1. Alphia R. Gataulina
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Damir A. Safin
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Timur R. Gimadiev
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Marina V. Pinus
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Damir A. Safin.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Gataulina, A.R., Safin, D.A., Gimadiev, T.R. et al. Complexes of podand-containing bis(dithiophosphonate) ligands with cobalt(II), nickel(II) and cadmium(II): recognition of CH2Cl2 . Transition Met Chem 33, 921–924 (2008). https://doi.org/10.1007/s11243-008-9133-4

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11243-008-9133-4

Keywords

Search

Navigation