Abstract
The kinetics of oxidation of ferrocyanide by N-bromosuccinimide (NBS) has been studied spectrophotometrically in aqueous acidic medium over temperature range 20–35 °C, pH = 2.8–4.3, and ionic strength = 0.10–0.50 mol dm−3 over a range of [Fe2+] and [NBS]. The reaction exhibited first order dependence on both reactants and increased with increasing pH, [NBS], and [Fe2+]. The rate of oxidation obeys the rate law: d[Fe3+]/dt = [Fe(CN)6]4–[HNBS+]/(k 2 + k 3/[H+]). An outer-sphere mechanism has been proposed for the oxidation pathway of both protonated and deprotonated ferrocyanide species. Addition of both succinimide and mercuric acetate to the reaction mixture has no effect on the reaction rate under the experimental conditions. Mercuric acetate was added to the reaction mixture to act as scavenger for any bromide formed to ensure that the oxidation is entirely due to NBS oxidation.
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References
Filler R (1963) Chem Rev 63:21
Kruse PF, Grist KL, McCoy TA (1954) Anal Chem 26:139
Lecomte J, Gault H (1954) Comp Rend 238:2538
Mathur NK, Narang CK (1975) The determination of organic compounds with n-bromosuccinimide. Academic Press, New York
Mushran SP, Pandey L, Singh K (1980) Monatsh Chem 111:1135
Singh B, Pandey L, Sharma J, Pandey SM (1982) Tetrahedron 38:169
Hedaya E, Hinman RL, Kibler LM, Theodoropulos S (1964) J Am Chem Soc 86:2727
Keonig T, Brewer W (1964) J Am Chem Soc 86:2728
Al-Shihri ASM, Abdel-Hady AEM (1996) Transition Met Chem 21:406
Abdel-Hady AEM, El-Shihri ASM (2001) Transition Met Chem 26:417
Abdel-Khalek AA, Sayyah SM, Khaled ESH (1993) Transition Met Chem 18:555
Abdel-Khalek AA, Khalil MM, Khaled ESH (1993) Transition Met Chem 18:153
Abdel-Khalek AA, Abdel-Hady AM, El-Shahat MF (1993) Transition Met Chem 18:283
Abdel-Khalek AA, Abdel-Hady ALEDM, El-Shahat MF (1994) Transition Met Chem 19:169
Ewais HA, Nagdy MA, Abdel-Khalek AA (2007) J Coord Chem 60(22):247
ElEzeri FR, Sulfab Y (1977) Inorganica Chem Acta 25:15
MCR Symons (1955) J Chem Soc 2794
Kasim AY, Sulfab Y (1977) Inorganica Chem Acta 22:169
Y Sulfab, HA Elfaki (1974) Can J Chem 52, 11
Kamble DL, Nandibewoor ST (1997) Polish J Chem 71:91
Kolthoff IM (1962) A. Anorg Allg Chem 1:587
Jordan J, Ewing GJ (1962) Inorg Chem 1:587
KH Hsu, SH Ho (1957) Kexue Torgbao 433
Lavison SA, Marcus RA (1968) J Phys Chem 72:358
Kassim AY, Sulfab Y (1977) Inorg Chem Acta 24:247
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Abdel-Hady, A.E.M. Kinetics and mechanism of oxidation of ferrocyanide by N-bromosuccinimide in aqueous acidic solution. Transition Met Chem 33, 887–892 (2008). https://doi.org/10.1007/s11243-008-9128-1
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DOI: https://doi.org/10.1007/s11243-008-9128-1