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Synthesis, characterization, and spectroscopic studies of palladium(II) and silver(I) complexes of 4-methoxybenzoylmethylenetriphenylphosphorane and 4-fluorobenzoylmethylenetriphenylphosphorane

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Abstract

The reactions of 4-methoxybenzoylmethylenetriphenylphosphorane ylide (MOBPPY), {(Ph)3PCHCOC6H4OMe}, and 4-flourobenzoylmethylenetriphenylphosphorane ylide (FBPPY) with [Pd(C6H4CH2NH2-κ2-C-N)ClL] (L = Py, 3-MePy, 4-MePy, or PPh3), in equimolar ratios in CH2Cl2 yield [Pd(C6H4CH2NH2-κ2-C-N)L (Ye)]TfO [(L = PPh3, Ye = MOBPPY; L = PPh3, Ye = FBPPY; L = Py, Ye = MOBPPY; or L = 3-MePy, Ye = MOBPPY]. The reaction of MOBPPY with AgOTf (OTf = CF3SO3) in molar ratios (2:1) using dry acetone as solvent gives [Ag(MOBPPY)2]OTf.

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  1. Department of Chemistry, Isfahan University of Technology, Isfahan, 84156/83111, I.R. Iran

    Kazem Karami

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  1. Kazem Karami
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Correspondence to Kazem Karami.

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Karami, K. Synthesis, characterization, and spectroscopic studies of palladium(II) and silver(I) complexes of 4-methoxybenzoylmethylenetriphenylphosphorane and 4-fluorobenzoylmethylenetriphenylphosphorane. Transition Met Chem 33, 819–823 (2008). https://doi.org/10.1007/s11243-008-9116-5

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  • DOI: https://doi.org/10.1007/s11243-008-9116-5

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