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Syntheses, crystal structures, and electrochemical properties of transition metal complexes with new tetrathiafulvalene-derivatized acetylacetonate ligands

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Abstract

Two new tetrathiafulvalene (TTF) derivatives of acetylacetone, namely, 3-[{6,7-benzo-2-(methylthio)-TTF-3-yl}-thio]-2,4-pentanedione (L1) and 3-[{6,7-(ethylenedithio)-2-(methylthio)-TTF-3-yl}-thio]-2,4-pentanedione (L2), have been synthesized. Four transition metal(II) complexes of these ligands, of general formulae [Zn(L1)2(THF)2] and [M(L2)2(THF)2] (M = Zn, Mn, and Ni), have been prepared and structurally characterized. The redox properties of both the ligands and their complexes were investigated by cyclic voltammetry.

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Acknowledgments

This work was supported by the Major State Basic Research Development Program (2006CB806104), the National Science Fund for Distinguished Young Scholars of China (Grant 20725104), and National Found for Fostering Talents of Basic Science (J0630425).

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Authors and Affiliations

  1. Coordination Chemistry Institute and the State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing, 210093, People’s Republic of China

    Peng Zheng, Yun-Jun Guo, Wei Liu, Yi-Zhi Li, Jing-Lin Zuo & Xiao-Zeng You

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  1. Peng Zheng
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  2. Yun-Jun Guo
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  3. Wei Liu
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  4. Yi-Zhi Li
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Correspondence to Jing-Lin Zuo.

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Peng Zheng and Yun-Jun Guo contributed equally to this work.

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Zheng, P., Guo, YJ., Liu, W. et al. Syntheses, crystal structures, and electrochemical properties of transition metal complexes with new tetrathiafulvalene-derivatized acetylacetonate ligands. Transition Met Chem 33, 767–773 (2008). https://doi.org/10.1007/s11243-008-9109-4

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