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Syntheses, structures and electrochemical properties of complexes of nickel(II) with triethylenetetramine and bidentate nitrogen donor co-ligands

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Abstract

Three new polyamine Ni(II) complexes, namely [Ni(trien)(phen)](BF4)2 1, [Ni(trien)(bipy)](ClO4)2 2 and [Ni(trien)(en)](ClO4)2 3 [trine = triethylenetetramine, phen = 1,10-phenanthroline, bipy = 2,2′-bipyridyl, en = ethylenediamine] have been synthesized and characterized by physico-chemical and spectroscopic methods. Complexes 1 and 2 crystallize in monoclinic space group P21/c, and possess a distorted octahedral geometry. Significant hydrogen bonding interactions are found in both complexes.

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Acknowledgements

Our grateful thanks are due to the National Diffraction Facility, X-ray Division, IIT Mumbai, for single crystal data collection. The Head RSIC, Central Drug Research Institute, Lucknow, is also thankfully acknowledged for providing analytical and spectroscopic facilities.

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  1. Department of Chemistry, A.P.S. University, Rewa, 486 003, M.P, India

    Ram N. Patel, Manoj K. Kesharwani, Anurag Singh, Dheerendra K. Patel & Mukesh Choudhary

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  1. Ram N. Patel
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  2. Manoj K. Kesharwani
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  3. Anurag Singh
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  4. Dheerendra K. Patel
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  5. Mukesh Choudhary
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Correspondence to Ram N. Patel.

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Patel, R.N., Kesharwani, M.K., Singh, A. et al. Syntheses, structures and electrochemical properties of complexes of nickel(II) with triethylenetetramine and bidentate nitrogen donor co-ligands. Transition Met Chem 33, 733–738 (2008). https://doi.org/10.1007/s11243-008-9104-9

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  • DOI: https://doi.org/10.1007/s11243-008-9104-9

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