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A new vic-dioxime ligand containing two azo substituents and its mononuclear nickel(II), cobalt(II), and copper(II) complexes; synthesis, characterization, spectroscopic and biological studies

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Abstract

A new vicinal dioxime ligand containing azo and thione chromophores, namely 1,3-bis[4-(phenyldiazenyl)phenyl]-2-thiooxaimidazoline-4,5-dione dioxime (bppH2), was synthesized by the reaction of cyanogen di-N-oxide with N,N′-bis(4-phenylazophenyl) thiourea in dichloromethane solution at −10 °C. Mononuclear complexes of bppH2 with nickel(II), cobalt(II), and copper(II) were synthesized. The complexes, [Ni(bppH)2], [Cu(bppH)2], and [Co(bppH)2] were characterized by several techniques using elemental analyses, conductivity measurements, FT-IR, and electronic spectral studies. The data suggest that the ligand coordinates through the N,N atoms, as do most vic-dioximes. The molar conductivities in DMF solution indicate nonelectrolytic nature for the complexes. Antimicrobial activities of the ligand and its metal complexes were estimated for five bacteria, namely Klebsiella pneumoniae, Micrococcus luteus, Mycobacterium smegmatis, Enterobacter cloaca and Bacillus megaterium and three fungi, namely Candida albicans, Kluyveromyces marxianus, and Rhodotorula rubra.

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Acknowledgment

The author thanks Research Found of Kahramanmaras Sutcu Imam University for financial support (project no: 2004/2-9), Kahramanmaras, Turkey.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Science and Arts, Kahramanmaraş Sütçü İmam University, 46050, Kahramanmaras, Turkey

    Mükerrem Kurtoğlu & Fatih Purtaş

  2. Department of Biology, Faculty of Science and Arts, Kahramanmaraş Sütçü İmam University, 46050, Kahramanmaras, Turkey

    Sevil Toroğlu

Authors
  1. Mükerrem Kurtoğlu
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  2. Fatih Purtaş
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  3. Sevil Toroğlu
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Correspondence to Mükerrem Kurtoğlu.

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Kurtoğlu, M., Purtaş, F. & Toroğlu, S. A new vic-dioxime ligand containing two azo substituents and its mononuclear nickel(II), cobalt(II), and copper(II) complexes; synthesis, characterization, spectroscopic and biological studies. Transition Met Chem 33, 705–710 (2008). https://doi.org/10.1007/s11243-008-9098-3

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  • DOI: https://doi.org/10.1007/s11243-008-9098-3

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