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Soft template synthesis in the cobalt(III)–1,2-diaminoethane-1,2-dithione–propanone triple system on a K[CoFe(CN)6]-gelatin-immobilized matrix

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Abstract

Complexation of CoIII, in the form of K[CoFe(CN)6]-gelatin-immobilized matrix, in contact with aqueous-alkaline solutions (pH ∼ 12) containing 1,2-diaminoethane-1,2-dithione and propanone, has been studied. Template synthesis leading to a chelate CoIII coordination compound with a tetradentate N,N,S,S-donor ligand identified as 4,4,6-trimethyl-1,9-diamino-1,9-dimercapto-3,7-diazanon-3-en-2,8-dithione and hydroxy co-ligand occurs under these specific conditions. 1,2-Diaminoethane-1,2-dithione and propanone are the ligand synthons in this process.

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Acknowledgements

Financial support from the Russian Foundation of Basic Researches (grant N 06-03-32003) is acknowledged. Also, the authors thank the Editor, Dr. M.C. Durrant for intensive editing of the manuscript of given article.

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Authors and Affiliations

  1. Analytical Chemistry, Certification and Quality Management Department, Kazan State Technological University, K.Marx Street 68, 420015, Kazan, Russia

    Oleg V. Mikhailov

  2. Department of Organic Chemistry, Kazan State University, Kremlin Street 18, 420008, Kazan, Russia

    Marina A. Kazymova

Authors
  1. Oleg V. Mikhailov
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  2. Marina A. Kazymova
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Correspondence to Oleg V. Mikhailov.

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Mikhailov, O.V., Kazymova, M.A. Soft template synthesis in the cobalt(III)–1,2-diaminoethane-1,2-dithione–propanone triple system on a K[CoFe(CN)6]-gelatin-immobilized matrix. Transition Met Chem 33, 523–527 (2008). https://doi.org/10.1007/s11243-008-9075-x

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  • DOI: https://doi.org/10.1007/s11243-008-9075-x

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