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Ligational behavior of new mononucleating SNOO thiosemicarbazone ligands towards 3d metal(II) ions: synthesis and spectroscopic studies

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Abstract

A series of three new mononucleating thiosemicarbazone ligands possessing potential S, N, and O coordination sites have been prepared by the reaction of 2-formylphenoxy acetic acid with substituted thiosemicarbazides. Complexes of these ligands with CoII, NiII, CuII, and ZnII have prepared and characterized by physico-chemical and spectroscopic methods. In all the complexes, the dibasic tetradentate nature of the ligand is evident.

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Acknowledgements

The authors thank the USIC, Karnatak University, Dharwad and B.V.B. Engineering College, Hubli for providing spectral facilities. The authors are thankful to Regional Sophisticated Instrumentation Center, Indian Institute of Technology, Bombay for recording e.p.r. spectra of the complexes and Sophisticated Instrumentation Facility, Indian Institute of Science, Bangalore, India for NMR and Solid State and Structural Chemistry Unit, Indian Institute of Science, Bangalore, India for recording magnetic susceptibility measurements.

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  1. Department of Chemistry, Karnatak University, Dharwad, 580 003, India

    Rajesh S. Baligar & Vidyanand K. Revankar

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  1. Rajesh S. Baligar
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  2. Vidyanand K. Revankar
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Correspondence to Vidyanand K. Revankar.

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Baligar, R.S., Revankar, V.K. Ligational behavior of new mononucleating SNOO thiosemicarbazone ligands towards 3d metal(II) ions: synthesis and spectroscopic studies. Transition Met Chem 33, 361–366 (2008). https://doi.org/10.1007/s11243-007-9051-x

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