Skip to main content
SpringerLink
Log in

Structural characterization of two lanthanide complexes attached to [H2W12O40]6−

  • Published:
Transition Metal Chemistry Aims and scope Submit manuscript

Abstract

In this article, two compounds [H2bpy][Ln(DMF)4(H2O)3(Hbpy)][H2W12O40] (Ln = La,Ce; DMF = N,N-dimethylformamide, bpy = 4,4′-bipyridine) have been synthesized and characterized by single-crystal X-ray diffraction, IR spectra, and TG analysis. X-Ray analysis showed that the [Ln(DMF)4(H2O)3(Hbpy)]4+ unit is supported on the α-Keggin polyoxoanion [H2W12O40]6− via the surface bridging oxygen atom. The [H2bpy][Ln(DMF)4(H2O)3(Hbpy)][H2W12O40] entity is further extended into 2D supramolecular networks with 1-D channels by hydrogen-bonding interactions, in which 4,4′-bipy ligands reside. To the best of our knowledge, these complexes represent the first examples of rare earth metal-organic complex-decorated α-metatungstate clusters. Furthermore, the electrochemical properties of these compounds have been studied via the method of bulk-modified carbon paste electrodes.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4

Similar content being viewed by others

References

  1. Müller A, Reuter H, Dillinger S (1995) Angew Chem Int Ed Engl 34:2328

    Article  Google Scholar 

  2. (a) Zhang C, Howell RC, Luo QH, Fieselmann HL, Todaro LJ, Francesconi LC (2005) Inorg Chem 44:3569; (b) Maayan G, Popovitz Biro R, Neumann R (2006) J Am Chem Soc 128:4968; (c) Kumar D, Derat E, Khenkin AM, Neumann R, Shaik S (2005) J Am Chem Soc 127:17712; (d) Kasai J, Nakagawa Y, Uchida S, Yamaguchi K, Mizuno N (2006) Chem Eur J 4176

  3. Cox PA (1995) Transition metal oxides. Clarendon Press, Oxford

    Google Scholar 

  4. Cheetham AJ (1994) Science 264:794

    Article  CAS  Google Scholar 

  5. (a) Pope MT, Müller A (1991) Angew Chem Int Ed Engl 103:56; (b) Xiutang Zhang, Daqi Wang, Jianmin Dou et al (2006) Inorg Chem 45:10629; (c) Dai LM, Ma Y, Wang EB, Lu Y, Xu XX, Bai XL (2006) Trans Met Chem 31:340; (d) Lu Y, Li YG, Ma Y, Wang EB and Xu XX (2006) Trans Met Chem 31:708; (e) Boglio C, Lemière G, Hasenknopf B, Thorimbert S, Lacôte E, Malacria M (2006) Angew Chem Int Ed 45:3324

  6. Long DL, Abbas H, Kögerler P, Cronin L (2005) Angew Chem Int Ed 44:3415

    Article  CAS  Google Scholar 

  7. Hagrman D, Haushalter RC, Zubieta J (1998) Chem Mater 10:361

    Article  CAS  Google Scholar 

  8. Hagrman D, Hagrman PJ, Zubieta J (1999) Comments Inorg Chem 21:225

    Article  CAS  Google Scholar 

  9. Zavalij P, Guo J, Whittingham MS, Jacobson RA, Pecharsky V, Bucher CK, Hwu SJ (1996) J Solid State Chem 123:83

    Article  CAS  Google Scholar 

  10. Khan MI, Cevik S, Doedens RJ, Chen Q, Li S, O’Connor CJ (1998) Inorg Chim Acta 277:69

    Article  CAS  Google Scholar 

  11. Ferey G (2000) J Solid State Chem 152:37

    Article  CAS  Google Scholar 

  12. Hagrman D, Zapf PJ, Zubieta J (1998) Chem Commun 1283

  13. DeBord JR, Haushalter RC, Meyer LM, Rose DJ, Zapf PJ, Zubieta J (1997) Inorg Chim Acta 256:165

    Article  CAS  Google Scholar 

  14. Tao J, Zhang XM, Tong ML, Chen XM (2001) J Chem Soc Dalton Trans 770

  15. Lin BZ, Liu SX (2002) Chem J Chin Univ 23:535

    CAS  Google Scholar 

  16. Lin BZ, Liu SX (2002) Chem Commun 2126

  17. Long DL, Blake AJ, Champness NR, Wilson C, Schroder M (2002) Chem Eur J 8:2026

    Article  CAS  Google Scholar 

  18. Long DL, Blake AJ, Champness NR, Schroder M (2000) Chem Commun 1369

  19. (a) Bünzli J-CG (1989) Lanthanide Probes in Life, Chemical and Earth Science; Elsevier, Amsterdam, 219; (b) Xu J, Raymond KN (2000) Angew Chem Int Ed 39:2745; (c) Jiang M, Zhai XD, Liu MH (2005) J Langmuir 11128:21; (d) Xu J, Raymond KN (2000) Angew Chem Int Ed 39:2745

  20. (a) Vaidhyanathan R, Natarajan S, Rao CNR (2001) Chem Mater 13:185; (b) Serre C, Férey G (2002) J Mater Chem 12:3053

  21. (a) Ribot F, Toledano P, Sanchez (1991) Inorg Chim Acta 185:239; (b) Panagiotopoulos A, Zafiropoulos TF, Perlepes SP, Bakalbassis E, Masson Ramade I, Kahn O, Terzis A, Raptopoulou CP (1995) Inorg Chem 34:4918

  22. Son JH, Kwon YU (2005) Inorg Chim Acta 358:310

    Article  CAS  Google Scholar 

  23. Higashi T (1999) Program for Absorption Correction. Rigaku Corporation, Tokyo

    Google Scholar 

  24. Sheldrick GM (1997) SHLEXL97, Programfor Crystal Structure Refinement, University of Göttingen, Germany

  25. Sheldrick GM (1997) SHLEXL97, Program for Crystal Structure Solution, University of Göttingen, Germany

  26. Hastings JJ, Howarth OW (1992) J Chem Soc Dalton Trans 209

  27. Launay JP, Boyer M, Chauveau FJ (1976) Inorg Nucl Chem 38:243

    Article  CAS  Google Scholar 

  28. Wang YH, Feng LY, Li YG, Wang EB et al (2002) Inorg Chem 41:6351

    Article  CAS  Google Scholar 

  29. Wang Y, Yu JH, Li Y et al (2003) Chem Eur J 9:5048

    Article  CAS  Google Scholar 

  30. Duan LY, Liu FC, Wang XL, Wang EB, Qin C (2004) J Mol Struct 705:15

    Article  CAS  Google Scholar 

  31. Wang XL, Wang EB, Lan Y, Hu CW (2002) Electroanalysis 14:1116

    Article  CAS  Google Scholar 

Download references

Acknowledgments

Supported by National Science Foundation of China (No. 20371011); Science and Technology Development Project Foundation of Jilin Province (No. 20060420); Analysis and testing foundation of Northeast Normal University (no. 201586000/201372000); and Ph.D station Foundation of Ministry of Education (No. 20060200002).

Author information

Authors and Affiliations

  1. Key Laboratory of Polyoxometalate Science of Ministry of Education, Department of Chemistry, Northeast Normal University, Changchun, 130024, P.R. China

    Hongli Chen, Yan Ding, Enbo Wang, Xinxin Xu, Yanfei Qi, Song Chang & Yangguang Li

  2. Department of Chemistry, Chengde Normal College, Chengde, 067000, P.R. China

    Hongli Chen

  3. Department of Biology Engineering, Jilin Business and Technology College, Changchun, 130062, P.R. China

    Yan Ding

Authors
  1. Hongli Chen
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Yan Ding
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Enbo Wang
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Xinxin Xu
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Yanfei Qi
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. Song Chang
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. Yangguang Li
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Enbo Wang.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Chen, H., Ding, Y., Wang, E. et al. Structural characterization of two lanthanide complexes attached to [H2W12O40]6− . Transition Met Chem 33, 341–346 (2008). https://doi.org/10.1007/s11243-007-9047-6

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11243-007-9047-6

Keywords

Search

Navigation