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Synthesis, X-ray crystal structures, and luminescent properties of two coordination polymers constructed from transition metal complexes of mixed flexible–rigid ligands

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Abstract

Two new coordination polymers [Ni(C6H10O4)(C10H8N2)] n (1) and [Zn3(C6H10O4)3(C12N2H8)2] n (2) have been synthesized under hydrothermal conditions. Complex (1) exhibits an interesting three-dimensional interpenetrating network, whereas complex (2) has a two-dimensional network. The IR and TG properties of these two complexes are studied. Furthermore, complex (2) exhibits photoluminescence.

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Acknowledgments

This work was supported by National Science Foundation of China (No. 20371011); Science and Technology Development Project Foundation of Jilin Province (No. 20060420); Analysis and testing foundation of Northeast Normal University (no. 201586000/201372000); PhD station Foundation of Ministry of Education (No. 20060200002).

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Authors and Affiliations

  1. Key Laboratory of Polyoxometalate Science of Ministry of Education, Department of Chemistry, Northeast Normal University, Changchun, 130024, P.R. China

    Yan Ding, Hongli Chen, Enbo Wang, Xinxin Xu, Xinlong Wang & Chao Qin

  2. Department of Biology Engineering, Jilin Business and Technology College, Changchun, 130062, P.R. China

    Yan Ding

  3. Department of Chemistry, Chengde Normal College, Chengde, 067000, P.R. China

    Hongli Chen

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  1. Yan Ding
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  2. Hongli Chen
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  3. Enbo Wang
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  4. Xinxin Xu
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  5. Xinlong Wang
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  6. Chao Qin
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Correspondence to Enbo Wang.

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Ding, Y., Chen, H., Wang, E. et al. Synthesis, X-ray crystal structures, and luminescent properties of two coordination polymers constructed from transition metal complexes of mixed flexible–rigid ligands. Transition Met Chem 33, 183–187 (2008). https://doi.org/10.1007/s11243-007-9035-x

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  • DOI: https://doi.org/10.1007/s11243-007-9035-x

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