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The synthesis and characterization of a new (E,E)-dioxime containing 18-membered dithiadiazadioxamacrocyclic moieties and its mononuclear complexes

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Abstract

A new (E,E)-dioxime, (21Z,22Z)-6,7,9,10,12,13-hexahydro-16H- benzo[h][1,4,7,16,10,13][1, 4,7,16,10,13]dioxadithiadiazacyclooctadecine-21,22(20H,23H)-dione dioxime (H 2 L) has been synthesized by reacting cyanogen-di-N-oxide (2) with (2-{[2-(2-{2-[(7-aminocyclohepta-1,4,6-trien-1-yl)thio]ethoxy}ethoxy)ethyl]thio}phenyl)amine. Mononuclear complexes of this ligand have been synthesized by reacting the vic-dioxime (H2L) with CuCl2, NiCl2.6H2O and CoCl2.6H2O respectively. The BF +2 capped Ni(II) and Co(III) complexes of the dioxime have been synthesized from. The new compounds were characterized by a combination of elemental analysis, 1H- and 13C-n.m.r, I.R. and m.s. spectral data.

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Acknowledgment

This study was supported by the Research Fund of Karadeniz Technical University, project no: 2006.111.002.1, (Trabzon-Turkey).

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Authors and Affiliations

  1. Department of Chemistry, Karadeniz Technical University, 61080, Trabzon, Turkey

    Halit Kantekin & Asiye Bakaray

  2. Department of Chemistry, Giresun University, Giresun, Turkey

    Zekeriya Bıyıklıoğlu & Meltem Betül Kılıçaslan

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  1. Halit Kantekin
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  2. Asiye Bakaray
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  3. Zekeriya Bıyıklıoğlu
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  4. Meltem Betül Kılıçaslan
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Correspondence to Halit Kantekin.

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Kantekin, H., Bakaray, A., Bıyıklıoğlu, Z. et al. The synthesis and characterization of a new (E,E)-dioxime containing 18-membered dithiadiazadioxamacrocyclic moieties and its mononuclear complexes. Transition Met Chem 33, 161–165 (2008). https://doi.org/10.1007/s11243-007-9026-y

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