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Synthesis and characterization of a novel Anderson-type tungstotellurate decorated by transition metal complexes: [Na(H2O)3]2[{Cu(2,2′-bipy)2}2(TeW6O24)] · 4H2O

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Abstract

A novel organic–inorganic hybrid tungstotellurate [Na(H2O)3]2[{Cu(2,2′-bipy)2}2(TeW6O24)] · 4H2O, has been synthesized and characterized by elemental analyses, IR spectra, TG analyses, and single-crystal X-ray diffraction. The saturated Anderson-type polyoxoanions are covalently bonded with two [Cu(2,2′-bipy)2]2+, and linked by Na+ into an infinite one-dimensional chain. Furthermore, the three-dimensional supramolecular architectures are formed by π–π stacking interactions of the 2,2′-bipyridine groups between adjacent layers and the hydrogen-bonding interactions respectively.

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Acknowledgment

The authors thank the National Natural Science Foundation of China (20171019) for financial support.

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Authors and Affiliations

  1. College of Chemistry and Chemical Engineering, State Key Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou, 730000, P.R. China

    Zhi-hong Xu, Pin-xian Xi, Feng-juan Chen & Zheng-zhi Zeng

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  1. Zhi-hong Xu
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  2. Pin-xian Xi
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  3. Feng-juan Chen
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  4. Zheng-zhi Zeng
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Correspondence to Zheng-zhi Zeng.

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Xu, Zh., Xi, Px., Chen, Fj. et al. Synthesis and characterization of a novel Anderson-type tungstotellurate decorated by transition metal complexes: [Na(H2O)3]2[{Cu(2,2′-bipy)2}2(TeW6O24)] · 4H2O. Transition Met Chem 33, 237–241 (2008). https://doi.org/10.1007/s11243-007-9004-4

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