Skip to main content
SpringerLink
Log in

Synthesis and characterization of some o,o′-dihydroxyazo dyes and their metal complexes

Transition Metal Chemistry volume 32, pages 1068–1072 (2007)Cite this article

Abstract

The synthesis and characterization of azo dyes containing o,o′-dihydroxy groups and their azo-metal(II) [Cu, Co, Ni, Zn] chelates by 1H N.M.R., IR, AAS, UV–VIS, magnetic susceptibility and thin-layer chromatography techniques are reported. The stochiometry of the azo-metal chelates was determined by the spectroscopic titration method to be 1:2 (ML2). The synthesized azo dyes and azo-metal chelate dyes were applied on wool fabric. Fastness to light and washing were measured.

This is a preview of subscription content, access via your institution.

Access options

Buy single article

Instant access to the full article PDF.

USD 39.95

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

References

  1. Blumel S., Knackmuss H.J. and Stolz A. (2002). Appl. Environ. Microbiol. 68: 3948

    Article  CAS  Google Scholar 

  2. Suzuki Y., Yoda T., Ruhul A. and Sugiura W. (2001). J. Biol. Chem. 276: 9059

    Article  CAS  Google Scholar 

  3. Peters A.T. and Freeman H.S. (1991). Colour Chemistry. The Design and Synthesis of Organic Dyes and Pigments. Elsevier App. Sci. Publ., Barking, Essex, 193–5

    Google Scholar 

  4. Gregory P. (1991). High-technology Applications of Organic Colorants. Plenum Press, New York and London, 1–3

    Google Scholar 

  5. Catino S.C. and Farris R.E. (1985). Azo dyes. In: Grayson, M. (eds) Concise Encyclopedia of Chemical Technology, pp 142. John Wiley & Sons, New York

    Google Scholar 

  6. Venkataraman K. (1970). The Chemistry of Synthetic Dyes, vol. 3. Academic press, New York and London, 303–69

    Google Scholar 

  7. Wang I.J., Husu Y.H. and Tian J.H. (1991). Dyes and Pigments 16: 83

    Article  CAS  Google Scholar 

  8. Hsieh B.R. (1990). Dyes and Pigments 14: 165

    Article  CAS  Google Scholar 

  9. Freeman H.S. and Sokolowska J. (1999). Rev. Prog. Coloration 29: 8

    Article  CAS  Google Scholar 

  10. Griffiths J. (1976). Colour and Constitution of Organic Molecules. Acedemic Press, New York and London, 193–5

    Google Scholar 

  11. Kocaokutgen H. and Özkınalı S. (2004). Dyes and Pigments 63: 83

    Article  CAS  Google Scholar 

  12. Kocaokutgen H., Erdem E. and Gümrükçüoğlu I.E. (1998). J. Soc. Dyers Colour 114: 93

    Article  CAS  Google Scholar 

  13. Kocaokutgen H. and Özkınalı S. (2004). Textile Res. J. 74(1): 78

    CAS  Google Scholar 

  14. Kocaokutgen H. and Erdem E. (2004). Synt. React. Inorg. Metal-Org. Chem. 34: 1843

    Article  CAS  Google Scholar 

  15. Dakiky M. and Memcova I. (1990). Dyes and Pigments 40: 141

    Article  Google Scholar 

  16. Hsieh B.R. and Desilets D. (1990). Dyes and Pigments 14: 165

    Article  CAS  Google Scholar 

  17. King R.B. (1965). Inorg. Chem. 5: 300

    Article  Google Scholar 

  18. Agarwal R.G. and Agarwal G.K. (1971). J. Indian Chem. Soc. 55: 681

    Google Scholar 

  19. Mahapatra B.B. and Mishra A.S.P. (1997). J. Indian Chem. Soc. 74: 218

    CAS  Google Scholar 

  20. Mahapatra B.B., Kar S.K., Pradhan S.P. and Bhoi P.K. (1992). J. Indian Chem. Soc. 69: 547

    CAS  Google Scholar 

  21. Mahapatra B.B., Mishra A.S.P. and Pradhan S.P. (1995). J. Indian Chem. Soc. 72: 721

    CAS  Google Scholar 

  22. Mahapatra B.B., Ray P. and Biswal B. (2001). As. J. Chem. 13: 949

    CAS  Google Scholar 

  23. Freemen F.B., Lee D.S. and Adele L.R. (1968). Infrared Spectra and Characteristic Frequencies. Interscience, New York

    Google Scholar 

  24. Powell E.P. and Sheppard N. (1961). Spectrochim. Acta 17: 68

    Article  CAS  Google Scholar 

  25. E.P. Powell and N. Sheppard, J. Chem. Soc., 1112 (1961).

  26. Lever A.B.P. (1968). Inorganic Electronic Spectroscopy. Elsevier, Amsterdam

    Google Scholar 

  27. Kılınçarslan R., Erdem E. and Kocaokutgen H. (2007). Transition Met. Chem. 32: 102

    Article  CAS  Google Scholar 

  28. Sacconi L. (1968). Transition Met. Chem. 61: 943

    Google Scholar 

  29. Sacconi L. (1968). Transition Met. Chem. 4: 212

    Google Scholar 

  30. Hill Z.D. and MacCharty P. (1986). J. Chem. Edu. 63: 162

    Article  CAS  Google Scholar 

  31. Rossotti F.J.C. and Rossotti H. (1961). The Determination of Stability Constants. McGraw-Hill Book Co. Inc., New York

    Google Scholar 

  32. Earnshaw A. (1968). Introduction to Magnetochemistry. Acedemic Press, London, 4

    Google Scholar 

  33. Law K.Y., Tarnawskyj I.W. and Lubberts P.T. (1993). Dyes and Pigments 23: 243

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Chemistry, Pamukkale University, Kiniklı Campus, Denizli, 20017, Turkey

    Nilgün Kabay, Emin Erdem, Rafet Kılınçarslan & Eylem Yıldırım Sarı

Authors
  1. Nilgün Kabay
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Emin Erdem
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Rafet Kılınçarslan
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Eylem Yıldırım Sarı
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Emin Erdem.

Rights and permissions

Reprints and Permissions

About this article

Cite this article

Kabay, N., Erdem, E., Kılınçarslan, R. et al. Synthesis and characterization of some o,o′-dihydroxyazo dyes and their metal complexes. Transition Met Chem 32, 1068–1072 (2007). https://doi.org/10.1007/s11243-007-0283-6

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11243-007-0283-6

Keywords

search

Navigation