Skip to main content
SpringerLink
Log in

Synthesis and magnetic properties of the novel binuclear copper(II) metallochelates with unsymmetrical exchange fragment including heterocyclic derivatives

  • Published:
Transition Metal Chemistry Aims and scope Submit manuscript

Abstract

The series of the novel copper(II) binuclear metallochelates with unsymmetrical exchange fragment including pyrazolate bridge has been synthesized for the first time. The composition and structure of the prepared compounds have been established with the data of UR, NMR-H1, EXAFS spectroscopy as well as magnetochemical studies. The analysis of the influence of pyrazolate ion on the magnetic exchange interaction between two copper atoms has been carried out.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Subscribe and save

Springer+ Basic
$34.99 /Month
  • Get 10 units per month
  • Download Article/Chapter or eBook
  • 1 Unit = 1 Article or 1 Chapter
  • Cancel anytime
Subscribe now

Buy Now

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Park J.H., Cizmar E. and Meisel M.W. (2004). J. Chem. Phys. 120: 1140

    Article  CAS  Google Scholar 

  2. Costa-Filho A., Moscimento O.B. and Ghivelder L. (2001). J. Chem. Phys. 105: 5039

    CAS  Google Scholar 

  3. Cairns C.J. and Busch D.H. (1986). Coord. Chem. Rev. 69: 1

    Article  Google Scholar 

  4. Kogan V.A., Lukov V.V., Levchenkov S.I., Antipin M.Yu. and Shishkin O.V. (1998). Mend. Comm. 4: 145

    Article  Google Scholar 

  5. O. Khan, Theoret. Approaches, 89 (1987)

  6. Ruiz E., Alemany P., Alvarez S. and Cano J. (1997). Inorg. Chem. 36: 3683

    Article  CAS  Google Scholar 

  7. Fallon G.O., Murray K.S. and Mazurek W.O. (1985). Inorg. Chim. Acta 96: 253

    Article  Google Scholar 

  8. B. Trivedi and P.K. Bhattachacharya, J. Chem. Soc. Res. Synop., 300 (1992)

  9. Nishida Y. and Küda S. (1988). Inorg. Chem. 27: 447

    Article  CAS  Google Scholar 

  10. P.E. Kruger, B. Monbaraki and K.S. Murray, J.Chem. Soc. Dalton Trans., 2129 (1994)

  11. Sanmartin J., Bermejo M.R., Garia-Deibe A.M., Maneiro M., Lage C. and Costa-Filho A.J. (2000). Polyhedron 19: 185

    Article  CAS  Google Scholar 

  12. Mikuriya M., Minowa K. and Nagao N. (2001). Bull. Chem. Soc. Jpn. 74: 871

    Article  CAS  Google Scholar 

  13. Kalinnikov V.T. and Rakitin Yu.V. (1994). Modern Magnetochemistry. Science, St-Petrsburg, 272

    Google Scholar 

  14. Yu.V. Rakitin (Ed.), in The Molecular Structure and Chemical Bond, VINITI, Moscow, 1986, p. 95

  15. Kahn O. (2000). Acc. Chem. Res. 33: 647

    Article  CAS  Google Scholar 

  16. Ruiz E., Alemany P., Alvarez S. and Cano J. (1997). J. Am. Chem. Soc. 119: 1297

    Article  CAS  Google Scholar 

  17. Lukov V.V., Kogan V.A., Tupolova Yu.P., Popov L.D., Gevorkyan I.E., Tkachev V.V., Shilov G.V. and Makitova D.D. (2004). Russian J. Inorg. Chem. 49: 1993

    CAS  Google Scholar 

  18. Kogan V.A., Lukov V.V., Novotorsev V.M., Tupolova Yu.P. and Gevorkyan I.E. (2005). Russian J. Coord. Chem. 31: 376

    Google Scholar 

  19. I.E. Gevorkyan, V.V. Lukov, V.A. Kogan, Yu.P. Tupolova and L.D. Popov, in Abst. VII International Seminar of Magnetic Resonance, Rostov-on-Don, 2004, p. 172

  20. Yu.P. Tupolova, V.V. Lukov, V.A. Kogan, V.M. Novotorsev, I.L. Eremenko, G.G. Alexandrov, I.E. Gevorkyan and L.D. Popov, Abst. XXII International Chugaev conference on Coord. Chem., Kishinev, 2005, p. 525

  21. Kogan V.A., Lukov V.V., Novotorsev V.M., Eremenko I.L. and Alexandrov G.G. (2005). Russ. Chem. Bull. Int. Ed. 54: 600

    Article  CAS  Google Scholar 

  22. Bleaney B. and Bowers K.D. (1952). Proc. R. Soc. Lond. Ser. A 214: 451

    Article  CAS  Google Scholar 

  23. Newville M. (2001). J. Synchrotron Rad. 8: 322–324

    Article  CAS  Google Scholar 

  24. Zabinsky S.I., Rehr J.J., Kvick A., Ancudinov A., Albers R.C. and Eller M.J. (1995). Phys. Rev. B52: 2995

    Google Scholar 

  25. Kavlakoglu E., Elmali A., Elerman Y. and Svoboda I. (2002). Polyhedron 21: 1539

    Article  CAS  Google Scholar 

  26. Chou Y.-C., Huang S.-F., Koner R., Lee G.-H., Wang Yu., Mohanta S. and Wei H.-H. (2004). Inorg. Chem. 43: 2759

    Article  CAS  Google Scholar 

  27. Y. Nishida and S. Kida V, Chem. Soc. Dalton Trans., 2633 (1986)

  28. S. Uhlenbrock, R. Wegner and B. Krebs, J. Chem. Soc. Dalton Trans., 3731 (1996)

  29. Mikariya Y., Sasaki T. and Anjiki A. (1992). Bull. Chem. Soc. Jpn. 62: 334

    Article  Google Scholar 

  30. Mikuriya M. and Minowa K. (2000). Inorg. Chem. Commun. 3: 227

    Article  CAS  Google Scholar 

  31. Mikuriya M., Nagao N. and Kondo K. (2000). Chem. Lett. 29: 516

    Article  Google Scholar 

  32. Mikuriya M., Minowa K. and Nagao N. (2001). Inorg. Chem. Commun. 4: 441

    Article  CAS  Google Scholar 

  33. L. Stelzig, A. Steiner, B. Chansou and J.-P. Tuchagues, Chem. Commun., 771 (1998)

  34. Solomon E.I. (2006). Inorg. Chem. 45: 8012

    Article  CAS  Google Scholar 

  35. Kalinnikov V.T., Rakitin Yu.V. and Novotorsev V.M. (2003). Uspekhi Khimii 72: 1123

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Chemistry, Rostov State University, 7, Zorge Str., Rostov-on-Don, 344090, Russian Federation

    Yu. P. Tupolova, V. A. Kogan, V. V. Lukov, L. D. Popov & I. E. Gevorkyan

  2. Institute of Physics, 194, Stachki Str., Rostov-on-Don, 344090, Russian Federation

    V. G. Vlasenko

Authors
  1. Yu. P. Tupolova
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. V. A. Kogan
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. V. V. Lukov
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. L. D. Popov
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. I. E. Gevorkyan
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. V. G. Vlasenko
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Yu. P. Tupolova.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Tupolova, Y.P., Kogan, V.A., Lukov, V.V. et al. Synthesis and magnetic properties of the novel binuclear copper(II) metallochelates with unsymmetrical exchange fragment including heterocyclic derivatives. Transition Met Chem 32, 656–661 (2007). https://doi.org/10.1007/s11243-007-0218-2

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11243-007-0218-2

Keywords

Search

Navigation