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Study on two coordination compounds using semicarbazide (SCZ) as bidentate ligand: \({[\hbox{Ni}(\hbox{SCZ})_{3}](\hbox{NO}_{3})_{2}}\) and \({\hbox{Cu}(\hbox{SCZ})_{2}\hbox{Cl}_{2}}\)

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Abstract

Two coordination compounds have been synthesized using semicarbazide as ligand- \({[\hbox{Ni}(\hbox{SCZ})_{3}](\hbox{NO}_{3})_{2}}\) (1) and \({\hbox{Cu}(\hbox{SCZ})_{2}\hbox{Cl}_{2}}\) (2). (1) crystallized as the monoclinic, P2(1)/c space group, a = 10.832(2) Å, b = 9.980(2) Å, c = 13.801(3) Å, β = 102.89(3)°; (2) crystallized as the monoclinic, P2(1)/c space group, a = 7.541(1) Å, b = 9.275(1) Å, c = 6.875(1) Å, β = 101.48(1)°. In both compounds, semicarbazides coordinate to nickel(II) or copper(II) centers to form the 5-member ring system. With the intermolecular hydrogen bonds, molecules are linked together to form the three-dimensional packing diagrams. Thermal decomposition mechanisms of both compounds were predicted based on DSC, TG-DTG and FTIR analyses.

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References

  1. Ivanov M.G. and Kalinichenko I.I. (1984). Zh. Neorg. Khim. 29: 926

    Google Scholar 

  2. Sindiskii V.P., Fogelzang A.E. and Dutov M.D. (1986). Russ. J. Inorg. Chem. 31: 1759

    Google Scholar 

  3. Lv C.H., Zhang T.L., Wei Z.R., Cai R.J. and Yu K.B. (1999). Chin. J. Inorg. Chem. 15: 377

    Google Scholar 

  4. Zhang J.G., Zhang T.L., Wei Z.R. and Yu K.B. (2001). Chem. J. Chin. Univers. 22: 895

    CAS  Google Scholar 

  5. Zhang T.L., Lv C.H., Qiao X.J., Cai R.J. and Yu K.B. (1999). Chin. J. Struct. Chem. 18: 432

    CAS  Google Scholar 

  6. Lv C.H., Zhang T.L., Qiao X.J., Cai R.J. and Yu K.B. (2000). Acta Phys. Chim. Sinica 16: 441

    Google Scholar 

  7. Ivanov M.G., Kaiinichenko I.I. and Pilipenko G.I. (1982). Koord. Khim. 8: 928

    CAS  Google Scholar 

  8. Ivanov M.G. and Kaiinichenko I.I. (1982). Zh. Neorg. Khim. 26: 2134

    Google Scholar 

  9. Ivanov M.G. and Kaiinichenko I.I. (1981). Zh. Neorg. Khim. 26: 2159

    CAS  Google Scholar 

  10. Dutta R.L. and Sarkar A.K. (1981). J. Inorg. Nucl. Chem. 43: 2557

    Article  CAS  Google Scholar 

  11. Sinditskii V.P., Veridub T.Y. and Fogelzang A.E. (1990). Zh. Neorg. Khim. 35: 685

    CAS  Google Scholar 

  12. Wei Z.R., Zhang T.L., Lv C.H. and Yu K.B. (1999). Chin. J. Inorg. Chem. 15: 482

    CAS  Google Scholar 

  13. Lv C.H., Zhang T.L., Wei Z.R. and Yu K.B. (1999). Chin. J. Inorg. Chem. 15: 377

    Google Scholar 

  14. Yang L., Zhang T.L., Zhang J.G., Shao B., Feng C.G. and Yu K.B. (2001). Chin. J. Energ. Mater. 9: 73

    CAS  Google Scholar 

  15. Ma G.X., Zhang T.L., Shao B., Zhang J.G., Song J.C., Li Y.F. and Yu K.B. (2004). Chin. J. Struct. Chem. 23: 445

    CAS  Google Scholar 

  16. Sheldrick G.M. (1990). Acta Cryst. A 46: 467

    Article  Google Scholar 

  17. Sheldrick G.M. (1997). SHELXL-97, Program for X-ray Crystal Structure Refinement. University of Göttingen, Germany

    Google Scholar 

  18. Nyquist R.A. and Kagel R.O. (1971). Infrared Spectra of Inorganic Compounds. Academic Press, New York, 220

    Google Scholar 

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Authors and Affiliations

  1. State Key Laboratory of Explosion Science and Technology, Beijing Institute of Technology, Beijing, 100081, P.R. China

    Jin-Yu Guo, Gui-Xia Ma, Tong-Lai Zhang, Jian-Guo Zhang & Yan-Hong Liu

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  1. Jin-Yu Guo
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  2. Gui-Xia Ma
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  3. Tong-Lai Zhang
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  4. Jian-Guo Zhang
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  5. Yan-Hong Liu
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Correspondence to Tong-Lai Zhang.

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Guo, JY., Ma, GX., Zhang, TL. et al. Study on two coordination compounds using semicarbazide (SCZ) as bidentate ligand: \({[\hbox{Ni}(\hbox{SCZ})_{3}](\hbox{NO}_{3})_{2}}\) and \({\hbox{Cu}(\hbox{SCZ})_{2}\hbox{Cl}_{2}}\) . Transition Met Chem 32, 413–418 (2007). https://doi.org/10.1007/s11243-006-0154-6

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  • DOI: https://doi.org/10.1007/s11243-006-0154-6

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