Abstract
Copper(II)-pyrrolidine dithiocarbamate (PDTC) complexes having the general formula, [Cu(PDTC)2], [Cu(PDTC)X2]− (where X = Cl−, I−, CN−, SCN−) and [Cu(PDTC)(en)]+ (en = ethylenediamine) have been prepared and characterized by IR spectroscopy and by thermogravimetric analysis (TGA and DTA). The IR data suggests that coordination of pyrrolidine dithiocarbamate (PDTC) takes place through the two sulphur atoms in a symmetrical bidentate fashion. The results of thermal analysis are consistent with the proposed composition of the complexes.
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Macias B., Villa M.V., Chicote E., Velasco S.M., Castineiras A. and Borras J. (2002). Polyhedron 21: 1899
Alverdi V., Giovagnini L., Marzano C., Serglia R., Bettio F., Sitran S., Graziani R. and Fregona D. (2004). J. Inorg. Biochem. 98: 1117
Faraglia G., Sitran S. and Montagner D. (2005). Inorg. Chim. Acta 358: 971
Ronconi L., Maccato C., Barreca D., Saini R., Zancato M. and Fregona D. (2005). Polyhedron 24: 521
Ronconi L., Giovagnini L., Marzano C., Bettio F., Graziani R., Pilloni G. and Fregona D. (2005). Inorg. Chem. 44: 1867
Magee R.J. and Hill J.O. (1985). Rev. Anal. Chem. 8: 5
Bond A.M. and Martin R.L. (1984). Coord. Chem. Rev. 54: 23
Rao A.L.J., Varma N., Kumar A. and Kapoor J. (1995). Chem. Environ. Res. 4: 163
Walker E.M., Hardin H.F., Gale G.L., Reifsteck M.E., Connon D.J. and Jones M.M. (1989). Res. Common, Chem. Path. Pharmacol. 63: 101
Lopez Garcia A., Blanco Gonzalez E. and Sanz-Medel A. (1996). Chromatographia 43: 607
Sarac S., Ertan M., Balkan A. and Yulua N. (1991). Arch. Pharm. 324: 449
Caruso F., Chan M.L. and Rossi M. (1997). Inorg. Chem. 36: 3609
Mital R., Jain N. and Srivastava T.S. (1989). Inorg. Chim. Acta 166: 135
Faraglia G., Fregona D., Sitran S., Giovagnini L., Marzano C., Baccichetti F., Casellato U. and Graziania R. (2001). J. Inorg. Biochem. 83: 31
Faraglia D., Sindellari L., Cerchi V., Furlani A., Papaioannou A. and Scarcia V. (1993). Transition Met. Chem. 18: 45
K. Lemma, S.K.C. Elmroth and L.I. Elding, J. Chem. Soc. Dalton. Trans., 1281 (2002)
Huang H., Zhu L., Reid B.R., Drobny G.P. and Hopkins P.B. (1995). Science 270: 1842
Bodenner D.L., Dedon P.C., Keng D.C. and Borch R.F. (1986). Cancer Res. 46: 2745
Fregona D., Giovagnini L., Ronconi L., Marzano C., Trevisan A., Sitran S., Biondi B. and Bordin F. (2003). J. Inorg. Biochem. 93: 181
Cuzzocrea S., Chatterjee P.K., Mazzon E. and Dugo L. (2002). Brit. J. Pharmacol. 135: 496
Kim S.H., Hans S.I., Oh S.Y. and Chung H.Y. et al. (2002). Biochem. Biophys. Res. Commun. 281: 367
Guadernak E., Speipelt J., Triendl A. and Grassaur A. et al. (2002). J. Virol. 76: 6004
Thomas S.R., Salahifar H., Mashima R. and Hunt N.H. et al. (2001). J. Immunol. 166: 6332
Bruck R., Aeed H., Schey R. and Matas Z. et al. (2002). J. Hepatol. 36: 370
Furuta S., Ortiz F., Sun X.Z. and Wu H.H. et al. (2002). Biochem. J. 365: 639
Atanasov A.G., Tam S., Rocken J.M., Baker M.E. and Odermatt A. (2003). Biochem. Biophy. Res. Commun. 308: 257
Brown D.A., Glass W.K. and Burke M.A. (1976). Spectrochim. Acta 32A: 137
Nakamoto K., Fujita J., Condrote R.A. and Morimoto Y. (1963). J. Chem. Phys. 39: 423
Durgaprasad G., Sathyanarayana D.N. and Patel C.C. (1969). Can. J. Chem. 47: 631
Criado J.J., Lopez J.A., Marcias B. and Lago L.R. (1992). Inorg. Chim. Acta 193: 229
Kellner R., Nikolov G.S. and Trendafilova N. (1984). Inorg. Chim. Acta 84: 233
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Sarwar, M., Ahmad, S., Ahmad, S. et al. Copper(II) complexes of pyrrolidine dithiocarbamate. Transition Met Chem 32, 199–203 (2007). https://doi.org/10.1007/s11243-006-0148-4
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DOI: https://doi.org/10.1007/s11243-006-0148-4