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Synthesis and spectral characterization of some new azo dyes and their metal complexes

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Abstract

A series of azo-metal chelate dyes have been synthesized by coupling substituted o-nitroaniline and p-t-/s-butylphenol. The spectral characterization of the azo dyes containing o-hydroxy group and azo-metal(II) chelate [metal(II): Cu, Ni, Co] dyes by IR spectra, UV–VIS spectra, NMR spectra, elemental analysis and magnetic susceptibility techniques are reported. The stoichiometry of the azo-metal chelates was determined by the spectroscopic titration method to be 1:2 (ML2).

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References

  1. Song H., Chen K., Wu D. and Tian H. (2004). Dyes Pigments 60: 111

    Article  CAS  Google Scholar 

  2. Tanaka K., Matsuo K., Nakanishi A., Jo M., Shiota H., Yamaguchi M., Yoshino S. and Kawaguchi K. (1984). Chem. Phar. Bull. 8: 3291

    Google Scholar 

  3. Hartman H. and Schulze M. (1991). Dyes Pigments 15: 255

    Article  Google Scholar 

  4. Peters A.T. and Chisowa E. (1993). Dyes Pigments 22: 223

    Article  Google Scholar 

  5. Mahapatra B.B., Kumar N.P.A. and Bhoi P.K. (1990). J. Indian Chem. Soc. 67: 800

    CAS  Google Scholar 

  6. Nishihara H. (2005). Coord. Chem. Rev. 249: 1468

    Article  CAS  Google Scholar 

  7. Wang S., Shen S., Xu H., Gu D., Yin J. and Tang X. (2000). Mater. Sci. Eng. B76: 69

    Article  CAS  Google Scholar 

  8. Wu S., Qian W., Xia Z., Zou Y., Wang S., Shen S. and Xu H. (2000). Chem. Phys. Lett. 330: 535

    Article  CAS  Google Scholar 

  9. Wang S., Shen S., Xu H., Gu D., Yin J. and Tang X. (1999). Dyes Pigments 42: 173

    Article  CAS  Google Scholar 

  10. Mahapatra B.B. and Mishra A.S.P. (1997). J. Indian Chem. Soc. 114: 93

    Google Scholar 

  11. King R.B. (1965). Inorg. Chem. 5: 300

    Article  Google Scholar 

  12. Agarwal R.G. and Agarwal G.K. (1971). J. Indian Chem. Soc. 55: 681

    Google Scholar 

  13. Mahapatra B.B., Kar S.K., Pradhan S.P. and Bhoi P.K. (1992). J. Indian Chem. Soc. 69: 547

    CAS  Google Scholar 

  14. Powell E.P. and Sheppard N. (1961). Spectro. Chim. Acta 17: 68

    Article  CAS  Google Scholar 

  15. E.P. Powell and N. Sheppard, J. Chem. Soc., 1112 (1961)

  16. Guozhen C. (1983). Ultraviolet-visible Spectroscopy (Part 1). Atomic Energy Press, Beijing

    Google Scholar 

  17. Sacconi L. (1968). Transition Met. Chem. 4: 212

    Google Scholar 

  18. Sacconi L. (1968). Transition Met. Chem. 61: 943

    Google Scholar 

  19. Hill Z.D. and MacCharty P. (1986). J. Chem. Edu. 63(2): 162

    Article  CAS  Google Scholar 

  20. Mahapatra B.B. and Mishra A.S.P. (1997). J. Indian Chem. Soc. 74: 218

    CAS  Google Scholar 

  21. Earnshaw A. (1968). Introduction to Magnetochemistry. Acedemic Press, London, 4

    Google Scholar 

  22. Kocaokutgen H. and Erdem E. (2004). Synthesis and Spectral Caracterization of Metal Complexes of 1-(2-hydroxy-4-methylphenolazo)-2-napthol synthesis and Reactivity in Inorganic and Metal Organic Chemistry 34(10): 1843

    CAS  Google Scholar 

  23. H. Kocaokutgen, E. Erdem and Gumrukçuoglu? The Society of Dyes and Colorists, USA, 114, 93 (1998)

Download references

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Authors and Affiliations

  1. Department of Chemistry, Pamukkale University, Kınıklı Campus, Denizli, Turkey

    Rafet Kılınçarslan & Emin Erdem

  2. Department of Chemistry, Ondokuz Mayıs University, Kurupelit, Samsun, Turkey

    Hasan Kocaokutgen

Authors
  1. Rafet Kılınçarslan
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  2. Emin Erdem
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  3. Hasan Kocaokutgen
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Correspondence to Emin Erdem.

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Kılınçarslan, R., Erdem, E. & Kocaokutgen, H. Synthesis and spectral characterization of some new azo dyes and their metal complexes. Transition Met Chem 32, 102–106 (2007). https://doi.org/10.1007/s11243-006-0134-x

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  • DOI: https://doi.org/10.1007/s11243-006-0134-x

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