Abstract
Binuclear cobalt(II), nickel(II), copper(II) and zinc(II) complexes of general composition [M2L1-2(μ-Cl)Cl2] · nH2O with the Schiff-base ligands (where L1H and L2H are the potential pentadentate ligands derived by condensing 2,6-diformyl-4-methylphenol with 4-amino-3-antipyrine and 2-hydroxy-3-hydrazinoquinoxiline, respectively) have been synthesized and characterized. Analytical and spectral studies support the above formulation. 1H-NMR and IR spectra of the complexes suggest they have an endogenous phenoxide bridge, with chloride as the exogenous bridge atom. The electronic spectra of all the complexes are well characterized by broad d–d and a high intensity charge-transfer transitions. The complexes are chloro-bridged as evidenced by two intense far-IR bands centered around 270–280 cm−1. Magnetic susceptibility measurements show that complexes are antiferromagnetic in nature. The compounds show significant growth inhibitory activity against fungi Aspergillus niger and Candida albicans and moderate activity against bacteria Bacillus cirroflagellosus and Pseudomonas auresenosa.
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References
D.E. Fenton H. Okawa (1977) Chem. Ber. Recueil. 130 433
T.N. Sorrell (1989) Tetrahedron 45 3 Occurrence Handle10.1016/0040-4020(89)80033-X Occurrence Handle1:CAS:528:DyaL1MXhvVClu7c%3D
D.G. Craciunescu (1977) An. R. Acad. Farm. 43 265 Occurrence Handle1:CAS:528:DyaE1cXjt1SitQ%3D%3D
J. Hosler C. Tschanz C.E. Hignite D.L. Azarnoff (1986) J. Invest. Dermatol. 74 51 Occurrence Handle10.1111/1523-1747.ep12514614
P.J. Meffin R.L. Williams T.F. Blaschke M. Rowland (1977) J. Pharm. Sci. 66 135 Occurrence Handle10.1002/jps.2600660140 Occurrence Handle1:CAS:528:DyaE2sXotlymuw%3D%3D
E.V. Schmidt, T.P. Priskchep and N.A. Chernova, IZV. Tomsk. Politekhm In-Ta., 156 (1975); M.M. Shoukry, A.Kh. Ghoneim and M.H. El-Nagdi, Synth. React. Inorg. Met. Org. Chem., 12, 815 (1982)
W. E-Dorfurt O. Schlcephake (1929) Z. Anorg. Allg. Chem. 183 301 Occurrence Handle10.1002/zaac.19291830122
W. E-Dorfurt H.G. Mureck (1930) Z. Anorg. Allg. Chem. 184 121 Occurrence Handle10.1002/zaac.19291840109
R. Rascanu (1933) Ann. Sci. Univ. Jassy. 18 72 Occurrence Handle1:CAS:528:DyaA2cXjvFSrug%3D%3D
J.V. Dubsky E. Krametz J. Trtilek (1936) Collection Czechoslov. Chem. Commun. 7 311
J.V. Dubsky E. Krametz J. Trtilek (1936) Collection Czechoslov. Chem. Commun. 8 141 Occurrence Handle1:CAS:528:DyaA28XjtlOltA%3D%3D
M. Ragno (1938) Gazz. Chim. Ital. 68 741 Occurrence Handle1:CAS:528:DyaA1MXitlCqsQ%3D%3D
Sh.T. Talipov A.T. Tashkhodzhaev L.E. Zel’tser Kh. Khilkmatov (1975) Izv. Vyssh. Ucheb. Zaved. Khim. Tekhnol. 15 1109
V.L. Letunov (1984) Zh. Org. Khim. 20 162 Occurrence Handle1:CAS:528:DyaL2cXktlynsrg%3D
K. Morishige (1980) Anal. Chim. Acta. 121 301 Occurrence Handle10.1016/S0003-2670(01)84427-5 Occurrence Handle1:CAS:528:DyaL3MXhtlWmsbk%3D
P. Zanello S. Tamburini P.A. Vigato G.A. Mazzocchin (1987) Coord. Chem. Rev. 77 165 Occurrence Handle10.1016/0010-8545(87)85034-8 Occurrence Handle1:CAS:528:DyaL2sXktFKmur8%3D
I. Bertini L. Messori M.S. Viezzoli (1992) Coord. Chem. Rev. 120 163 Occurrence Handle10.1016/0010-8545(92)80050-2 Occurrence Handle1:CAS:528:DyaK3sXlsVequg%3D%3D
S.L. Lambert D.N. Hendrickson (1979) Inorg. Chem. 18 2683 Occurrence Handle10.1021/ic50200a009 Occurrence Handle1:CAS:528:DyaE1MXls1Onsb0%3D
P. Cheng S.P. Yan D.Z. Liao L.J. Bai Z.H. Jiang G.L. Wang (1994) Chin. J. Chem. 12 314 Occurrence Handle1:CAS:528:DyaK2MXlvVGquw%3D%3D Occurrence Handle10.1002/cjoc.19940120404
P. Cheng S.P. Yan D.Z. Liao Z.H. Jiang G.L. Wang (1995) Polyhedron 14 2355 Occurrence Handle10.1016/0277-5387(95)00062-W Occurrence Handle1:CAS:528:DyaK2MXotVWisbc%3D
D.A. Denton and H. Suschitzky, J. Chem. Soc., 4741 (1963)
E.R. Quijano E.D. Steven C.J.O. Connor (1990) Inorg. Chim. Acta 177 267 Occurrence Handle10.1016/S0020-1693(00)85985-X Occurrence Handle1:CAS:528:DyaK3MXhvFynu7w%3D
E.E. Educk C.J.O. Connor (1984) Inorg. Chim. Acta 88 229 Occurrence Handle10.1016/S0020-1693(00)83602-6
P.K. Radhakrishnan P. Indrasenan C.G.R. Nair (1984) Polyhedron 3 67 Occurrence Handle10.1016/S0277-5387(00)84714-2 Occurrence Handle1:CAS:528:DyaL2cXks1Crt7Y%3D
L. Guofa N. Chongwu L. Bin M. Kunyuan (1990) Polyhedron 9 2019 Occurrence Handle10.1016/S0277-5387(00)84030-9
S.K. Agarwal J.P. Tandon (1979) Monatsh. Chem. 110 401 Occurrence Handle10.1007/BF00911928 Occurrence Handle1:CAS:528:DyaE1MXks1OksrY%3D
W.E. Estes J.R. Wasson J.W. Hass W.E. Hatfield (1978) Inorg. Chem. 17 3657 Occurrence Handle10.1021/ic50190a063 Occurrence Handle1:CAS:528:DyaE1cXmt1Gjt7Y%3D
R. Jagannathan S. Soundararajan (1981) Inorg. Nucl. Chem. Lett. 17 65 Occurrence Handle10.1016/0020-1650(81)80028-1 Occurrence Handle1:CAS:528:DyaL3MXksFeqt7s%3D
I.E. Dickson R.R. Robson (1974) Inorg. Chem. 13 1301 Occurrence Handle10.1021/ic50136a010 Occurrence Handle1:CAS:528:DyaE2cXkt1Sgtrc%3D
R.B. Coles C.M. Harris E. Sihn (1969) Inorg. Chem. 12 2608
H. Okawa S. Kida (1972) Bull. Chem. Soc. Jpn. 45 1759 Occurrence Handle10.1246/bcsj.45.1759 Occurrence Handle1:CAS:528:DyaE38XkvVejur8%3D
R.C. Long D.N. Hendrickson (1983) J. Am. Chem. Soc. 105 1513 Occurrence Handle10.1021/ja00344a018 Occurrence Handle1:CAS:528:DyaL3sXhtFynurk%3D
H. Okawa J. Nishio M. Ohba M. Tadokoro N. Matsumoto M. Koikawa D.E. Fenton S. Kida (1993) Inorg. Chem. 32 2949 Occurrence Handle10.1021/ic00065a025 Occurrence Handle1:CAS:528:DyaK3sXks1WlsLk%3D
(a) S.J. Gruber and C.M. Harris, Inorg. Nucl. Chem. Lett., 30, 1805 (1968); (b) M. Honda, Helv. Chim. Acta, 40, 27 (1957); (c) R.L. Belford, Mol. Phys., 5, 251 (1962); (d) L. Sacconi, J. Chem. Soc., 276 (1964)
B. Bosnich (1968) J. Am. Chem. Soc. 90 627 Occurrence Handle10.1021/ja01005a012 Occurrence Handle1:CAS:528:DyaF1cXksVegtw%3D%3D
H. Furutachi H. Okawa (1997) Inorg. Chem. 36 3911 Occurrence Handle10.1021/ic9700563 Occurrence Handle1:CAS:528:DyaK2sXlsVOgtrs%3D
F.A. Faweett, E.E. Bernarducci, K.K. Jespersen and H.J. Schugar, J. Am. Chem. Soc., 102, 2598 (1980); J.V. Dagdgian, V. McKee and C.A. Reed, Inorg. Chem., 21, 1332 (1982)
T.N. Sorrell, D.L. Jameson and C.J. O’Connor, Inorg. Chem., 23, 190 (1984); Y. Nishida, H. Shimo, H. Maehara and S. Kida, J. Chem. Soc. Dalton Trans., 1945, (1985); H.P. Berends and D.W. Stephan, Inorg. Chem., 26, 749 (1987); S. Schindler, D.J. Szalda and C. Creutz, Inorg. Chem., 31, 2255 (1992)
Y. Nishida S. Kida (1976) Inorg. Nucl. Chem. Lett. 38 451 Occurrence Handle10.1016/0022-1902(76)80282-5 Occurrence Handle1:CAS:528:DyaE28XhsVaktLk%3D
H. Okawa, M. Tadokoro, Y. Aratake, M. Ohba, K. Shindo, M. Mitsumi, M. Tomono and D.E. Fenton, J. Chem. Soc. Dalton Trans., 253, (1993)
M. Handa T. Idehara K. Nakano K. Kasuga M. Mikuriya N. Matsmoto M. Kodera S. Kida (1992) Bull Chem. Soc. Jpn. 65 3241 Occurrence Handle10.1246/bcsj.65.3241 Occurrence Handle1:CAS:528:DyaK3sXhsF2rsLw%3D
R.S. Himmelwright N.C. Eickman E.I. Solomon (1979) J. Am. Chem. Soc. 101 1576 Occurrence Handle10.1021/ja00500a034 Occurrence Handle1:CAS:528:DyaE1MXhs1emtb8%3D
H. Adams, D.E. Fenton, S.R. Haque, M. Ohba, H. Okawa and S.E. Spey, J. Chem. Soc. Dalton Trans., 1849, (2000)
H. Okawa, S. Kida, Y. Muto and T. Tokii, Bull. Chem. Soc. Jpn., 45, 2480 (1972); H. Okawa, S. Kida, Y. Muto and T. Tokii, Bull. Chem. Soc. Jpn., 46, 1462 (1973)
C. Chow R.D. Willett B.C. Gerstine (1975) Inorg. Chem. 13 205 Occurrence Handle10.1021/ic50143a047
M.D. Glick R.L. Vintredt (1976) Prog. Inorg. Chem. 21 233 Occurrence Handle1:CAS:528:DyaE28Xhslejtrw%3D
(a) M. Handa, N. Koga and S. Kida, Bull. Chem. Soc. Jpn. 11, 3853 (1988); (b) H. Astheimer and W. Hasse, J. Chem. Phys., 85, 1427 (1986)
T. Mallah O. Khan J. Jeannin S. Jeannin C.J. O’Connor (1987) Inorg. Chem. 26 1375 Occurrence Handle10.1021/ic00256a008 Occurrence Handle1:CAS:528:DyaL2sXhs1OktLk%3D
H. Okawa T. Tokh Y. Nonaka Y. Muto S. Kida (1973) Bull. Chem. Soc. Jpn. 46 1462 Occurrence Handle10.1246/bcsj.46.1462 Occurrence Handle1:CAS:528:DyaE3sXkt1KlsbY%3D
M.C. Jain A.K. Srivastava P.C. Jain (1977) Inorg. Chem. Acta. 23 199 Occurrence Handle10.1016/S0020-1693(00)94761-3 Occurrence Handle1:CAS:528:DyaE2sXkvFCksbg%3D
M. Shakir S.P. Varkey I.S. Hameed (1994) Polyhedron 13 1355 Occurrence Handle10.1016/S0277-5387(00)81701-5 Occurrence Handle1:CAS:528:DyaK2cXls1yquro%3D
J.M. Vincent (1947) Nature 189 850
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Annigeri, S.M., Sathisha, M.P. & Revankar, V.K. Spectroscopic studies of bridged binuclear complexes of Co(II), Ni(II), Cu(II) and Zn(II). Transition Met Chem 32, 81–87 (2007). https://doi.org/10.1007/s11243-006-0131-0
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DOI: https://doi.org/10.1007/s11243-006-0131-0