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Phenanthroline complexes bearing diamide-anion recognition sites

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Abstract

The synthesis and anion binding properties of new ruthenium(II) and cobalt(II) phenanthroline complexes, containing two amide subunits are described. Evidence for anion binding in dimethyl sulfoxide (DMSO) solution was obtained from u.v.–vis titration experiments. Results indicated that these receptors showed strong affinity for F− and AcO−, and showed weak affinity for OH− and H2PO −4 , and showed no affinity for Cl−, Br−, I−. These receptors interacted with various anions examined through hydrogen-bond formation.

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Authors and Affiliations

  1. Department of Chemistry, Nankai University, Tianjin, 300071, P.R. China

    Xue-Fang Shang & Hua-Kuan Lin

  2. State Key Laboratory of Functional Polymer Materials for Absorption and Separation, Nankai University, Tianjin, 300071, P.R. China

    Hai Lin

Authors
  1. Xue-Fang Shang
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  2. Hua-Kuan Lin
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  3. Hai Lin
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Correspondence to Hua-Kuan Lin.

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Shang, XF., Lin, HK. & Lin, H. Phenanthroline complexes bearing diamide-anion recognition sites. Transition Met Chem 32, 38–41 (2007). https://doi.org/10.1007/s11243-006-0124-z

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  • DOI: https://doi.org/10.1007/s11243-006-0124-z

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