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Synthesis, spectral characterization and catalytic applications of Ru(II) complexes with amide ligands

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Abstract

Ruthenium(II) complexes of the type, RuCl2(NO)(PPh3)(L2) (where L = amide ligand) have been synthesized and characterized on the basis of their elemental analysis IR, 1H-, 13C-, 31P-NMR spectra. Amide ligand behaved as a bidentate ligand. The probable structures of these complexes have been discussed. They were used as catalysts for the hydrolysis of drugs viz. rivastigmine tartrate and neostigmine bromide. The percent yields of hydrolyzed products of these drugs were determined spectrophotometrically.

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Authors and Affiliations

  1. Department of Chemistry, Kakatiya University, Warangal, 506 009, India

    More Ashok & Vadde Ravinder

  2. Department of Chemistry, National Institute of Technology, Warangal, 506 004, India

    Adapa V. S. S. Prasad

Authors
  1. More Ashok
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  2. Vadde Ravinder
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  3. Adapa V. S. S. Prasad
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Correspondence to Vadde Ravinder.

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Ashok, M., Ravinder, V. & Prasad, A.V.S.S. Synthesis, spectral characterization and catalytic applications of Ru(II) complexes with amide ligands. Transition Met Chem 32, 23–30 (2007). https://doi.org/10.1007/s11243-006-0123-0

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  • DOI: https://doi.org/10.1007/s11243-006-0123-0

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