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Synthesis and physicochemical characterization of zinc(II) and cadmium(II) complexes with simple ligands

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Abstract

In order to study the physicochemical properties of ZnII and CdII complexes, complexes with “simple” supporting ligands were synthesized. Various coordination types were obtained, such as ZnN2S2 in [Zn(SCH2CF3)2(L)] (L = sp, ( − )-sparteine or hp, homopiperazine), ZnN2O2 in [Zn(OCH(CF3)2)2(sp)], ZnO2S2 in (Et4N)2 [Zn(OCH2(CF2)3CH2O)(SCH2CF3)2], ZnN3S in [Zn(SR)(tacniPr)](ClO4) (tacniPr = 1,4,7-triisopropyl-1,4,7-triazacyclononane; SR = 1-adamantanethiolate, SC10H15, 1-cyclohexanethiolate, SC6H11, or SCH2CF3), CdN3S in [Cd(SC10H15)(tacniPr)](ClO4) and [Cd3(SCH2CF3)6(tacniPr)2]. The far-i.r., Raman and u.v.–vis. absorption spectra of the complexes are discussed, and the crystal structures of two of the complexes were determined.

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Authors and Affiliations

  1. Graduate School of Pure and Applied Sciences, University of Tsukuba, Tsukuba, 305-8571, Japan

    Yuki Matsunaga, Kiyoshi Fujisawa, Nagina Amir, Yoshitaro Miyashita & Ken-ichi Okamoto

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  1. Yuki Matsunaga
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  2. Kiyoshi Fujisawa
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  3. Nagina Amir
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  4. Yoshitaro Miyashita
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  5. Ken-ichi Okamoto
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Correspondence to Kiyoshi Fujisawa.

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Matsunaga, Y., Fujisawa, K., Amir, N. et al. Synthesis and physicochemical characterization of zinc(II) and cadmium(II) complexes with simple ligands. Transition Met Chem 31, 897–906 (2006). https://doi.org/10.1007/s11243-006-0085-2

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  • DOI: https://doi.org/10.1007/s11243-006-0085-2

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