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Synthesis and Characterization of Halo, Cyanato, Thiocyanato and Selenocyanato Molybdenum(VI) Dioxo and Dioxo-μ-oxo Complexes

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Abstract

Ten new 4,4′-bipyridyl molybdenum(VI) dioxo and dioxo-μ-oxo complexes have been synthesized and fully characterized. The substituents on the bipyridyl moiety are: t-butyl, benzyl, carbomethoxy, nitro and methoxy groups, whereas the functional ligands on molybdenum are: chloro, bromo, thiocyanato, cyanato and selenocyanato groups. The molecular structure of three of them have been determined by single crystal X-ray crystallography and showed distortions from an octahedral geometry in accord with the nature of the various substituents.

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Authors and Affiliations

  1. UMR 6180 CNRS, Université Paul Cézanne, Aix Marseille III, 13397, Marseille, France

    Henri Arzoumanian & Robert Bakhtchadjian

  2. Instituto Venezolano de Investigaciones Científicas Apartado, 21827, Caracas, Venezuela

    Giuseppe Agrifoglio, Reinaldo Atencio & Alexander Briceño

Authors
  1. Henri Arzoumanian
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  2. Robert Bakhtchadjian
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  3. Giuseppe Agrifoglio
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  4. Reinaldo Atencio
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  5. Alexander Briceño
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Correspondence to Henri Arzoumanian.

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Arzoumanian, H., Bakhtchadjian, R., Agrifoglio, G. et al. Synthesis and Characterization of Halo, Cyanato, Thiocyanato and Selenocyanato Molybdenum(VI) Dioxo and Dioxo-μ-oxo Complexes. Transition Met Chem 31, 681–689 (2006). https://doi.org/10.1007/s11243-006-0049-6

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  • DOI: https://doi.org/10.1007/s11243-006-0049-6

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