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Synthesis and Single-crystal Structures of Two Copper(II) Complexes and One Iron(II) Complex Prepared by in situ Ligand Substitution at Room Temperature

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Abstract

Two hexa-coordinate copper(II) complexes formulated as [Cu(phen)(4-dmampy)2(ClO4)2] and [Cu(bpy)(3-ampy)2(ClO4)2] · 0.5CH3OH · 0.5H2O (phen = 1,10–phenanthroline bpy = 2,2′-bipyridine, 3-ampy = 3-aminopyridine, 4-dmampy = 4-dimethylaminopyridine), and one low-spin ferrous complex formulated as [Fe(dmbpy)3](ClO4)2 · H2O (dmbpy = 4,4′-dimethyl-2,2′-bipyridine), were synthesized by in situ ligand substitution at room temperature, and characterized by X-ray single-crystal diffraction. This is the first structural report where either 4-dmampy and phen molecules, or 3-ampy and bpy molecules, are located simultaneously around one metal center.

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Authors and Affiliations

  1. State Key Laboratory of Coordination Chemistry, Coordination Chemistry Institute, Nanjing University, Nanjing, 210093, P.R. China

    Wei Huang

  2. College of Sciences, Nanjing University of Technology, Nanjing, 210009, P.R. China

    Huifen Qian

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  1. Wei Huang
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  2. Huifen Qian
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Correspondence to Wei Huang.

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Huang, W., Qian, H. Synthesis and Single-crystal Structures of Two Copper(II) Complexes and One Iron(II) Complex Prepared by in situ Ligand Substitution at Room Temperature. Transition Met Chem 31, 621–629 (2006). https://doi.org/10.1007/s11243-006-0039-8

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  • DOI: https://doi.org/10.1007/s11243-006-0039-8

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