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Effect of Added Pyridine Bases on the Electron Transfer Reaction of Chromium(VI) with Organic Sulfides. Spectral Evidence for the Formation of a Chromium(V) Intermediate

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Abstract

The electron transfer reaction of Cr(VI) with organic sulfides is facilitated by added pyridine bases 2,2′-bipyridine, 1,10-phenanthroline, picolinic acid and pyridine 2,6-dicarboxylic acid. The added base forms a Cr(VI)-base adduct carrying positive charge which acts as a more reactive oxidant compared to Cr(VI). UV–Visible spectrophotometric study provides evidence for the formation of Cr(V) as the intermediate. The reactions in the absence and presence of pyridine bases follow the reactivity–selectivity principle.

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Authors and Affiliations

  1. Department of Chemistry, S.T. Hindu College, Nagercoil, 629 002, India

    Thiruneelakandan Chockalingam Manohar

  2. School of chemistry, Madurai Kamaraj University, Madurai, 625 021, India

    Muthuraman Rajkumar & Seenivasan Rajagopal

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  1. Thiruneelakandan Chockalingam Manohar
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  2. Muthuraman Rajkumar
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  3. Seenivasan Rajagopal
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Correspondence to Seenivasan Rajagopal.

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Manohar, T.C., Rajkumar, M. & Rajagopal, S. Effect of Added Pyridine Bases on the Electron Transfer Reaction of Chromium(VI) with Organic Sulfides. Spectral Evidence for the Formation of a Chromium(V) Intermediate. Transition Met Chem 31, 549–555 (2006). https://doi.org/10.1007/s11243-006-0028-y

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