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Synthesis, Characterization and Crystal Structure of a One-dimensional Diamagnetic Metal-radical Complex: [Zn(NIT4py)2(DTB)2(H2O)2]

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Abstract

A novel one-dimensional complex [Zn(NIT4py)2(DTB)2(H2O)2] (1), with mixed ligands [where NIT4py is 2-(4′-pyridyl)-4,4,5,5-tetramethylimidazoline-1-oxyl-3-oxide and DTB is 3,5-dinitrobenzoate] has been synthesized and characterized by elemental analyses, i.r., u.v.–vis spectra, thermogravimetric analysis, X-ray single crystal diffraction and magnetic measurements. The complex crystallizes in the triclinic crystal system and space group Pî. The ZnII ion is in a distorted octahedral environment: two nitrogen atoms from two NIT4py entities, two oxygen atoms from two DTB units in the basal plane; and two oxygen atoms from the two water molecules in the axial position. The [Zn(NIT4py)2(DTB)2(H2O)2] units are connected as a one dimension chain by the intermolecular hydrogen bonds. The complex exhibits intramolecular antiferromagnetic interactions between the two radicals.

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Authors and Affiliations

  1. School of Materials Science and Engineering, Tianjin University, Tianjin, 300072, People’s Republic of China

    Chen-Xi Zhang & Jing Sheng

  2. Department of Chemistry, Nankai University, Tianjin, 300071, People’s Republic of China

    Yu Ying Zhang

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  1. Chen-Xi Zhang
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  2. Jing Sheng
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  3. Yu Ying Zhang
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Correspondence to Chen-Xi Zhang.

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Zhang, CX., Sheng, J. & Zhang, Y.Y. Synthesis, Characterization and Crystal Structure of a One-dimensional Diamagnetic Metal-radical Complex: [Zn(NIT4py)2(DTB)2(H2O)2]. Transition Met Chem 31, 93–96 (2006). https://doi.org/10.1007/s11243-005-6346-7

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  • DOI: https://doi.org/10.1007/s11243-005-6346-7

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