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Unsymmetrical Tetradentate Schiff Base Complexes Derived from 2,3-diaminophenol and Salicylaldehyde or 5-bromosalicylaldehyde

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Abstract

Salicylaldehyde or 5-bromosalicylaldehyde reacted with 2,3-diaminophenol in absolute EtOH in a 2:1 molar ratio to give new unsymmetrical Schiff bases (H2L). The bases were used as ligands to coordinate Mn(III), Ni(II) and Cu(II) chlorides leading to [MnIIIClL] · EtOH and [MIIL] or [MIIL] · 2H2O (M = Ni or Cu) complexes. Their structures were determined using mass spectroscopy, IR, u.v.–vis and 1H-n.m.r. The cyclic voltammetry in acetonitrile showed irreversible waves for both ligands. Under the same experimental conditions, the complexes exhibited mainly the non-reversible reduction of the Ni(II) or Cu(II) ion to Ni(0) or Cu(0), while the reduction of Mn(III) to Mn(II) was found to be a quite reversible phenomenon.

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Authors and Affiliations

  1. Laboratoire d’Electrochimie, d’Ingénierie Moléculaire et de Catalyse Rédox (LEIMCR), Faculté des Sciences de l’Ingénieur, Université Ferhat Abbas, DZ-19000, Sétif, Algeria

    Ali Ourari, Kamel Ouari, Wahiba Moumeni & Lakhdar Sibous

  2. SONAS, E.A. 921, Faculté de Pharmacie, 16 Boulevard Daviers, F-49045, Cedex 01, Angers, France

    Gilles M. Bouet & Mustayeen A. Khan

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  1. Ali Ourari
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  2. Kamel Ouari
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  3. Wahiba Moumeni
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  4. Lakhdar Sibous
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Correspondence to Gilles M. Bouet.

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Ourari, A., Ouari, K., Moumeni, W. et al. Unsymmetrical Tetradentate Schiff Base Complexes Derived from 2,3-diaminophenol and Salicylaldehyde or 5-bromosalicylaldehyde. Transition Met Chem 31, 169–175 (2006). https://doi.org/10.1007/s11243-005-6334-y

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