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Synthesis and characterization of a complex salt and heterobimetallic coordination polymers of 1-benzoyl-1-cyanoethylene-2,2-dithiolate

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Abstract

The complex salt (NBu n4 )2 [Cu(bcd)2] and heterobimetallic coordination polymers MM′(bcd)2 [M=2AgI, CdII, HgII or PbII; M′=NiII or CuII; bcd2−=1-benzoyl-1-cyanoethylene-2,2-dithiolate] have been synthesized from the reaction of Na2[M′(bcd)2] generated in situ with NBu n4 Br or metal salts MX2 [X=MeCO −2 , NO −3 , Cl− or SO 2−4 ]. The complexes were characterized by elemental analyses, molar conductance, magnetic susceptibility, i.r., n.m.r., electronic and e.s.r. spectra and solid-state conductivity measurements. The MCu(bcd)2 polymers are diamagnetic, suggesting strongly antiferromagnetically coupled CuII ions. The conductivities of the pressed pellets of the compounds are very small and they do not show semiconducting behaviour in the considered temperature range.

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  1. Akhilesh Prasad Sunita Gupta

    Present address: Department of Physical and Inorganic Chemistry, Indian Institute of Science (I.I.Sc.), Bangalore, 12, India

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  1. Department of Chemistry, Banaras Hindu University, Varanasi, 221005, India

    Nanhai Singh

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  1. Nanhai Singh
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  2. Akhilesh Prasad Sunita Gupta
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Singh, N., Gupta, A.P.S. Synthesis and characterization of a complex salt and heterobimetallic coordination polymers of 1-benzoyl-1-cyanoethylene-2,2-dithiolate. Transition Met Chem 30, 383–388 (2005). https://doi.org/10.1007/s11243-004-6968-1

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